Results 21 to 30 of about 291,669 (391)

Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides [PDF]

, 2011
A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures.
Aggarwal, Alexakis, Allan, Allan J. B. Watson, Anderson, Aoki, Aoki, Aoki, Aoki, Bassindale, Blümke, Brownbridge, Brownbridge, Bunn, Bunn, Bunn, Busch-Petersen, Carswell, Clegg, Conway, Corey, Cousins, Eaton, Eaton, Graf, Graf, Gronnow, Hama, Henderson, Henderson, Henderson, Henderson, Henderson, Hodgson, Ila, Kerr, Kerr, Kerr, Knochel, Leitner, Linsey S. Bennie, Melzig, Michael Middleditch, Mulvey, Navarro, Netherton, Sato, Shirai, Shirai, Simpkins, Simpkins, Westerhausen, William J. Kerr, Wunderlich, Çalimsiz   +54 more
core   +1 more source

High-performance light-emitting diodes based on carbene-metal-amides [PDF]

Science, 2016
Adding a twist for enhanced performance The efficiency of organic light-emitting diodes (OLEDs) is fundamentally governed by the ratio of emissive singlet to dark triplet excitons that are formed from spin-polarized electron and hole currents within the ...
D. Di, A. Romanov, Le Yang, Johannes M. Richter, Jasmine P. H. Rivett, Saul T. E. Jones, Tudor H. Thomas, Mojtaba Abdi Jalebi, R. Friend, Mikko Linnolahti, M. Bochmann, D. Credgington   +11 more
semanticscholar   +1 more source

Tandem aza-Claisen rearrangement and ring closing metathesis reactions: the stereoselective synthesis of functionalised carbocyclic amides [PDF]

, 2009
A one-pot, tandem process has been developed for the efficient synthesis of functionalised carbocyclic amides. A substituted cyclopentenyl trichloroacetamide was synthesised using a tandem thermal aza-Claisen rearrangement and RCM process, while an ...
Donaldson, A., Sutherland, A., Swift, M.D.   +2 more
core   +1 more source

5-Chloroisoxazoles: A Versatile Starting Material for the Preparation of Amides, Anhydrides, Esters, and Thioesters of 2H-Azirine-2-carboxylic Acids

Molecules, 2022
Amides, anhydrides, esters, and thioesters of 2H-azirine-2-carboxylic acids were prepared by a rapid procedure at room temperature involving FeCl2-catalyzed isomerization of 5-chloroisoxazoles to 2H-azirine-2-carbonyl chlorides, followed by reaction with
Anastasiya V. Agafonova, Mikhail S. Novikov, Alexander F. Khlebnikov   +2 more
doaj   +1 more source

Asymmetric synthesis of γ-chloro-α,β-diamino- and β,γ-aziridino-α-aminoacylpyrrolidines and -piperidines via stereoselective Mannich-type additions of N-(diphenylmethylene)glycinamides across α-chloro-N-sulfinylimines [PDF]

, 2012
The asymmetric synthesis of new chiral gamma-chloro-alpha,beta-diaminocarboxylamide derivatives by highly diastereoselective Mannich-type reactions of N-(diphenylmethylene) glycinamides across chiral alpha-chloro-N-p-toluenesulfinylaldimines was ...
Augustyns, Koen, Callebaut, Gert, De Kimpe, Norbert, Mangelinckx, Sven, Tornroos, Karl W, Van der Veken, Pieter   +5 more
core   +3 more sources

AMIDES ISOLATED FROM THE LEAVES OF Piper tuberculatum Jacq. (Piperaceae) WITH ACETYLCHOLINESTERASE INHIBITION AND LARVICIDAL ACTIVITY AGAINST Aedes aegypti [PDF]

Química Nova
Piper tuberculatum Jacq. is known to be a promising source of amides, which have shown remarkable biological activities. In this study, a phytochemical investigation of the leaves of P.
Brenda R. C. Leocadio, Taynara S. Vale, Felipe M. A. da Silva, João V. C. O. Santos, Sergio M. Nunomura, André C. de Oliveira, Ingrity S. C. Sá, Rosemary A. Roque, Ana Paula A. Castro, Magno P. Muniz, Rita C. S. Nunomura   +10 more
doaj   +1 more source

One-Pot Synthesis of Single-Source Precursors for Nanocrystalline LED Phosphors M2Si5N8:Eu2+ (M = Sr, Ba) [PDF]

, 2009
Highly efficient red-emitting nitridosilicate phosphors Sr2Si5N8:Eu2+ and Ba1.5Sr0.5Si5N8:Eu2+ (doping level 1%) applicable to phosphor converted pc-LEDs were synthesized in nanocrystalline form at low temperatures employing a novel single-source ...
Schmidt, Peter J., Schnick, Wolfgang, Zeuner, Martin   +2 more
core   +1 more source

Homoleptic Bis(trimethylsilyl)amides of Yttrium Complexes Catalyzed Hydroboration Reduction of Amides to Amines.

Organic Letters, 2020
Homoleptic lanthanide complex Y[N(TMS)2]3 is an efficient homogeneous catalyst for the hydroboration reduction of secondary amides and tertiary amides to corresponding amines. A series of amides containing different functional groups such as cyano, nitro,
Pengqing Ye, Yinlin Shao, X. Ye, Fangjun Zhang, Renhao Li, Jiani Sun, Beihang Xu, Jiuxi Chen   +7 more
semanticscholar   +1 more source

An efficient method for the construction of polysubstituted 4-pyridones via self-condensation of β-keto amides mediated by P2O5 and catalyzed by zinc bromide

Beilstein Journal of Organic Chemistry, 2013
A self-condensation cyclization reaction mediated by phosphorus pentoxide (P2O5) and catalyzed by zinc bromide (ZnBr2) is presented for the synthesis of polysubstituted 4-pyridones and 2-pyridones from β-keto amides.
Liquan Tan, Peng Zhou, Cui Chen, Weibing Liu   +3 more
doaj   +1 more source

Fully Chlorinated N-Silyl Amides of Titanium and Tungsten [PDF]

, 1997
The reaction of hexachlorodisilazanyllithium (Cl3Si)2NLi (1), with TiCl4 leads selectively to the novel fully chlorinated amides (Cl3Si)2NTiCl3 (2) or [(Cl3Si)2N]2 TiCl2 (3), respectively, depending on the molar ratio of the starting materials.
Milius, Wolfgang, Schnick, Wolfgang, Schwarze, Bernd   +2 more
core   +1 more source