Results 11 to 20 of about 4,376 (210)
Synthesis and Reactivity of Ynamine Amidines [PDF]
Ynamine amidines can be synthesized from the 1,3-dichlorotrimethine cyanine and primary amines. Ammonia affords the reactive ynamine amidine having a free imino group. This compound cyclises readily with carbon dioxide and phenylisocyanate.
B. Caillaux +4 more
doaj +2 more sources
Copper-Catalyzed Aerobic [3+2]-Annulation of N-Alkenyl Amidines
A method for the synthesis of bi- and tricyclic amidines has been developed through copper-catalyzed aerobic [3+2]-annulation reaction of N-alkenyl amidines.
Shunsuke Chiba (1670473) +2 more
core +6 more sources
The 'ins' and 'outs' of amidines in β-sheet folding and fibril disaggregation. [PDF]
Amidines are a relatively unexplored isostere of the amide bond, offering unique electronic properties and hydrogen-bonding behavior. This study presents the first systematic investigation of amidines within folded β-sheet structures.
O'Brien EA +3 more
europepmc +2 more sources
A Modular Synthesis of C5-Sulfenyl Thiazoles via an Intermolecular Pummerer Rearrangement: An Underexplored Scaffold for Medicinal Chemistry. [PDF]
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Smy JL +5 more
europepmc +3 more sources
A series of novel cobalt bis(dicarbollide) based amidines were synthesized by the nucleophilic addition of primary and secondary amines to highly activated B-N+≡C–R triple bond of the propionitrilium derivative [8-EtC≡N-3,3′-Co(1,2-C2B9H10)(1′,2′-C2B9H11)
Ekaterina V. Bogdanova +4 more
doaj +1 more source
Syntheses and molecular structures of some di(amidino)monosilanes
The syntheses of three different amidinosilanes of the type Me2Si[N=C(Ph)R]2 with R = pyrrolidino, morpholino, and diethylamino and one derivative with the composition R2Si[N=C(Ph)R]2 with R = morpholino are reported. These compounds were prepared in one-
Bös Markus +3 more
doaj +1 more source
Allyl halides with triflamide under oxidative conditions form halogen-substituted amidines. Allyl cyanide reacts with triflamide in acetonitrile or THF solutions in the presence of NBS to give the products of bromotriflamidation with a solvent ...
Anton S. Ganin +4 more
doaj +1 more source
SYNTHESIS OF DERIVATIVES OF MERCAPTO AMIDINES AMIDES AND NITRILES.
SYNTHESIS OF DERIVATIVES OF MERCAPTO AMIDINES AMIDES AND ...
THOMAS LAURENCE. WELSH (7977872)
core +6 more sources
N-Sulfonyl amidines bearing 1,2,3-triazole, isoxazole, thiazole and pyridine substituents were successfully prepared for the first time by reactions of primary, secondary and tertiary heterocyclic thioamides with alkyl- and arylsulfonyl azides.
Vladimir Ilkin +7 more
doaj +1 more source
Modern chemical disinfectants and antiseptics. Part I
Aim. To generalize and systematize information on the properties of modern chemical disinfectants and antiseptic agents (DA and AA). Results and discussion.
Vasyl M. Britsun +3 more
doaj +1 more source

