Results 11 to 20 of about 4,376 (210)

Synthesis and Reactivity of Ynamine Amidines [PDF]

open access: yesCHIMIA, 1976
Ynamine amidines can be synthesized from the 1,3-dichlorotrimethine cyanine and primary amines. Ammonia affords the reactive ynamine amidine having a free imino group. This compound cyclises readily with carbon dioxide and phenylisocyanate.
B. Caillaux   +4 more
doaj   +2 more sources

Copper-Catalyzed Aerobic [3+2]-Annulation of N-Alkenyl Amidines

open access: yes, 2016
A method for the synthesis of bi- and tricyclic amidines has been developed through copper-catalyzed aerobic [3+2]-annulation reaction of N-alkenyl amidines.
Shunsuke Chiba (1670473)   +2 more
core   +6 more sources

The 'ins' and 'outs' of amidines in β-sheet folding and fibril disaggregation. [PDF]

open access: yesChem Sci
Amidines are a relatively unexplored isostere of the amide bond, offering unique electronic properties and hydrogen-bonding behavior. This study presents the first systematic investigation of amidines within folded β-sheet structures.
O'Brien EA   +3 more
europepmc   +2 more sources

A Modular Synthesis of C5-Sulfenyl Thiazoles via an Intermolecular Pummerer Rearrangement: An Underexplored Scaffold for Medicinal Chemistry. [PDF]

open access: yesAngew Chem Int Ed Engl
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Smy JL   +5 more
europepmc   +3 more sources

Synthesis of Boronated Amidines by Addition of Amines to Nitrilium Derivative of Cobalt Bis(Dicarbollide)

open access: yesMolecules, 2021
A series of novel cobalt bis(dicarbollide) based amidines were synthesized by the nucleophilic addition of primary and secondary amines to highly activated B-N+≡C–R triple bond of the propionitrilium derivative [8-EtC≡N-3,3′-Co(1,2-C2B9H10)(1′,2′-C2B9H11)
Ekaterina V. Bogdanova   +4 more
doaj   +1 more source

Syntheses and molecular structures of some di(amidino)monosilanes

open access: yesMain Group Metal Chemistry, 2021
The syntheses of three different amidinosilanes of the type Me2Si[N=C(Ph)R]2 with R = pyrrolidino, morpholino, and diethylamino and one derivative with the composition R2Si[N=C(Ph)R]2 with R = morpholino are reported. These compounds were prepared in one-
Bös Markus   +3 more
doaj   +1 more source

Triflamidation of Allyl-Containing Substances:Unusual Dehydrobromination vs. Intramolecular Heterocyclization

open access: yesMolecules, 2022
Allyl halides with triflamide under oxidative conditions form halogen-substituted amidines. Allyl cyanide reacts with triflamide in acetonitrile or THF solutions in the presence of NBS to give the products of bromotriflamidation with a solvent ...
Anton S. Ganin   +4 more
doaj   +1 more source

SYNTHESIS OF DERIVATIVES OF MERCAPTO AMIDINES AMIDES AND NITRILES.

open access: yes, 1963
SYNTHESIS OF DERIVATIVES OF MERCAPTO AMIDINES AMIDES AND ...
THOMAS LAURENCE. WELSH (7977872)
core   +6 more sources

Regioselective synthesis of heterocyclic N-sulfonyl amidines from heteroaromatic thioamides and sulfonyl azides

open access: yesBeilstein Journal of Organic Chemistry, 2020
N-Sulfonyl amidines bearing 1,2,3-triazole, isoxazole, thiazole and pyridine substituents were successfully prepared for the first time by reactions of primary, secondary and tertiary heterocyclic thioamides with alkyl- and arylsulfonyl azides.
Vladimir Ilkin   +7 more
doaj   +1 more source

Modern chemical disinfectants and antiseptics. Part I

open access: yesЖурнал органічної та фармацевтичної хімії, 2021
Aim. To generalize and systematize information on the properties of modern chemical disinfectants and antiseptic agents (DA and AA). Results and discussion.
Vasyl M. Britsun   +3 more
doaj   +1 more source

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