Results 101 to 110 of about 597,754 (265)

Beyond the Fixed Charge: A New On‐Tissue Derivatisation Strategy Employing Photoionisable Chromophores for Mass Spectrometry Imaging of Amino‐Containing Metabolites

Angewandte Chemie, EarlyView.
We introduce a novel chemical derivatisation strategy for the UV‐activated detection of elusive metabolites. Incorporation of a tocopherol‐active chromophore allows for the detection of tagged analytes as photoionised radical cations, selectively induced by a 266 nm laser.
Sofia R. McGowan, Andrew J. Tague, Ashna A. Kumar, Marie Ranson, Christopher J. T. Hyland, Shane R. Ellis   +5 more
wiley   +2 more sources

Nucleophilic Aromatic Substitution Reactions in Water Enabled by Micellar Catalysis

, 2015
Given the huge dependence on dipolar, aprotic solvents such as DMF, DMSO, DMAc, and NMP in nucleophilic aromatic substitution reactions (SNAr), a simple and environmentally friendly alternative is reported. Use of a “benign-by-design” nonionic surfactant,
Fabrice Gallou (1520266), Sean M. Kelly (1520272), Bruce H. Lipshutz (1330881), Nicholas A. Isley (1520275), Roscoe T. H. Linstadt (1520269)   +4 more
core   +1 more source

Local Order Is Not Enough: Synthetically Accessible Polymers Reveal the Role of Side‐chain Branching Point in Organic Solar Cell and Transistor Performance

Advanced Electronic Materials, EarlyView.
Systematic variation of the side‐chain branching point in a series of donor polymers reveals that moving the branch further from the backbone improves local crystal quality but reduces the overall degree of crystallinity, leading to progressively worse organic solar cell and transistor performance.
Martina Rimmele, Xabier Rodríguez‐Martínez, Zhuoran Qiao, Kaiyang Wei, Adam V. Marsh, Julianna Panidi, Nicola Gasparini, Jaime Martin, Martin Heeney   +8 more
wiley   +1 more source

[O─I─O]+ Halogen‐Bonded Complexes of Pyridine N‐Oxides

Angewandte Chemie, EarlyView.
The missing puzzle of 3‐center‐4‐electron halogen‐bonded complexes viz. [O─I─O]+ of pyridine N‐oxides are structurally characterized by x‐ray diffraction. Monodentate N‐oxide O‐atom acts as the halogen bond acceptor. Their solution complexations are characterized by 15N NMR spectroscopy.
Rakesh Puttreddy, Sergi Burguera, Antonio Frontera, Kari Rissanen   +3 more
wiley   +2 more sources

Exploring the Orthogonal Chemoselectivity of 2,4,6-Trichloro-1,3,5-Triazine (TCT) as a Trifunctional Linker With Different Nucleophiles: Rules of the Game

Frontiers in Chemistry, 2018
The study involves exploring the three orthogonal sites for aromatic nucleophilic substitution in cyanuric chloride (TCT). The preferential order of incorporation of different nucleophiles (such as alcohol, thiol, and amine) was addressed both ...
Anamika Sharma, Anamika Sharma, Ayman El-Faham, Ayman El-Faham, Beatriz G. de la Torre, Fernando Albericio, Fernando Albericio, Fernando Albericio, Fernando Albericio   +8 more
doaj   +1 more source

Synthesis of organosoluble and light-colored cardo polyimides via aromatic nucleophilic substitution polymerization

, 2015
A series of cardo polyimides (PIs) containing large-volume cardo groups were prepared via aromatic nucleophilic substitution polymerization of bisphenols and bis(fluorophthalimide)s.
Mushtaq, Nafeesa, Chen, Guofei, Liu, Jiangtao, Fang, Xingzhong   +3 more
core  

Multiscale Design of Anion Exchange Membrane‐Based Seawater Electrolysis for Sustainable Hydrogen Production

Advanced Energy Materials, EarlyView.
Direct seawater electrolysis using anion exchange membranes is emerging as a promising route for sustainable hydrogen production. This review summarizes multiscale design strategies from seawater chemistry and OER–ClER selectivity to catalysts, membranes, MEAs, cells, stacks, and system integration, providing a roadmap toward selective, durable, and ...
Chiho Kim, Geunhee Yuk, Jong‐Hyeok Park, Shin‐woo Myeong, Jun Seok Ha, Won Tae Hong, Jung Kyu Kim, Sung Mook Choi   +7 more
wiley   +1 more source

Visible‐Light‐Induced Carbon–Hydrogen Phosphonylation of Conjugated Polymers via Electron Donor–Acceptor Complex Activation

Angewandte Chemie, EarlyView.
Electron donor–acceptor (EDA) complex activation enabled the efficient transformation of conjugated polymers. Compared with the small‐molecule model compound, the polymers reacted more efficiently, achieving quantitative conversion of PFO. This result demonstrates a new platform for incorporating conjugated polymers into EDA‐mediated photochemical ...
Tomohiro Tamano, Kohei Taniguchi, Yoichiro Eriguchi, Kosuke Sato, Shinsuke Inagi   +4 more
wiley   +2 more sources

Harnessing the Reactivity of Sulfinate Salts With Cystine: An Umpolung Approach to Residue‐Specific Peptide Modification

Angewandte Chemie, EarlyView.
While cysteine is widely employed as a nucleophilic handle for peptide modification, the electrophilicity of the oxidized form, cystine, is rarely exploited. This study describes a mild, photochemical coupling of sulfinate salts with peptide disulfides.
Joshua M. Hammond, Esteban Suárez‐Picado, Lena von Sydow, Hanna Bruss, Laurent Knerr, Magnus Johansson, Anaïs Noisier, Lara R. Malins   +7 more
wiley   +2 more sources

Kinetically Stable Boron‐Heteroatom Bonds

Angewandte Chemie, EarlyView.
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova, Ben Zhen Huang, Harjeet S. Soor, Brandon White, Aleksandra Holownia, Yury Lebedev, Alan J. Lough, Travis Dudding, Andrei K. Yudin   +8 more
wiley   +2 more sources