Results 121 to 130 of about 89,167 (310)

An Electrophilic Uridine Building Block for Post‐Synthetic RNA Modification as Exemplified for Spin Labeling

open access: yesChemistry – A European Journal, EarlyView.
An electrophilic 5‐isothiocyanatomethyl uridine building block enables modular post‐synthetic RNA labeling with primary amine‐containing probes. Positioning the functionality in the major groove minimizes structural perturbation and allows facile conjugation of sensitive tags such as TEMPO spin labels for paramagnetic relaxation enhancement studies ...
Lisa Ruetz   +4 more
wiley   +1 more source

Environmental Stresses and Redox Status of Ascorbate [PDF]

open access: yes, 2003
To investigate the effects of environmental stresses on ascorbic acid content and its redox status, the effects of freezing and drought on ascorbate and dehydro-ascorbate content and activities of four enzymes involved in the ascorbate-glutathione cycle ...
Da-Li Tao   +6 more
core   +3 more sources

Ascorbate Oxidase

open access: yesJournal of Biological Chemistry, 1973
M H, Lee, C R, Dawson
openaire   +2 more sources

Tribochemical Surface Modification of Silicon

open access: yesChemistry – A European Journal, EarlyView.
Mechanical scribing activates silicon surfaces by generating reactive sites that spontaneously graft alcohol‐, thiol‐, and alkyne‐terminated molecules under ambient conditions. Within 10 s, high‐coverage, electroactive organic layers form without light, heat, or applied voltage, offering a rapid tribochemical route to functional silicon interfaces for ...
Abdulrahman O. Abdulrahman   +6 more
wiley   +1 more source

Karrikins Regulate the Redox Balance and Sugar Metabolism of Postharvest Kiwifruit (Actinidia deliciosa)

open access: yesPlants
Karrikins, a class of butenolide compounds derived from plant-derived smoke, positively regulate plant development and stress tolerance. However, their effects on postharvest fruit have scarcely been reported.
Mingxia Shao   +4 more
doaj   +1 more source

Efficient Light‐Driven Multi‐Electron Accumulation on Viologens by Molecular Control Over Photochemical Reaction Pathways

open access: yesChemistry – A European Journal, EarlyView.
Minimum structural changes, maximum output: By either utilizing a more oxidizing Ru(II) polypyridyl chromophore or by using a more reducing SED, the photocatalytic reduction of methyl viologen (MV2+) proceeds via a reductive quenching pathway. This not only significantly accelerates the overall photoreduction process but also allows accumulation of ...
Fatemeh Sousani   +7 more
wiley   +1 more source

Epigenetic Reprogramming via TET2 Prevents Medial Calcification and Restores Vascular Smooth Muscle Cell Identity

open access: yesJACC: Basic to Translational Science
Summary: Vascular calcification arises from the osteogenic transdifferentiation of vascular smooth muscle cells (VSMCs) and is a hallmark of many cardiovascular pathologies.
Bob S.L. Lee, PhD   +14 more
doaj   +1 more source

ASCORBATE-LINKED NANOSYSTEMS FOR BRAIN DELIVERY [PDF]

open access: yes, 2010
The invention is based, at least in part, on the discovery of a method for targeting liposomes and micelles to brain cells. This discovery was exploited to develop the invention, which, in one aspect, features a method of delivering a lipid formulation ...
SALMASO, STEFANO   +2 more
core  

Nitrogen‐Site Isomerism Unlocks Exciton Dissociation in Vinylene‐Linked COF‐Based Photocatalysts

open access: yesEcoEnergy, EarlyView.
Two regioisomeric vinylene‐linked covalent organic frameworks (COFs) constructed from diazine units with different nitrogen positions are developed for photocatalytic hydrogen evolution reaction (HER). Although structurally similar, the isomeric COFs exhibit distinct electron distribution and charge‐separation behaviors, leading to a more than twofold ...
Ming Wang   +10 more
wiley   +1 more source

Exploring the Anticancer Activity of Ruthenium(II)–Arene and Copper(I) Complexes Bearing N‐Heterocyclic Carbene Ligands Containing Azido, Pyridinium, and Ethisterone‐Derived Triazole Groups

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
A versatile library of backbone‐functionalized N‐heterocyclic carbene (NHC) ligands was developed and efficiently converted into Cu(I) and Ru(II) NHC complexes, demonstrating that ligand functionalization strongly modulates anticancer activity, with Cu(I)–NHC species showing potent and selective antiproliferative effects against ovarian and breast ...
Alessia Schiavo   +4 more
wiley   +1 more source

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