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The inhibition of caeruloplasmin by azide [PDF]

open access: greenBiochemical Journal, 1966
1. The inhibition of the oxidase activity of caeruloplasmin by azide was investigated at 25 degrees and 7.5 degrees . 2. The inhibition is reversible on dilution or Sephadex treatment, indicating a caeruloplasmin-azide complex. 3. The enzyme is protected against azide inhibition by chloride, acetate or EDTA, the last-named acting not by chelation but ...
G. Curzon
openalex   +4 more sources

Bis(azido-κN)bis(quinolin-8-amine-κ2N,N′)iron(II) monohydrate [PDF]

open access: yesIUCrData
In the hydrated title complex, [Fe(N3)2(AQ)2]·H2O (AQ is 8-aminoquinoline, C9H9N2), the FeII ion is coordinated in a distorted octahedral manner by two neutral, chelating AQ ligands and two anionic, monodentate azide (N3−) ions in a syn,cis-configuration.
Fatima Setifi   +4 more
doaj   +2 more sources

Facile fabrication of polymer network using click chemistry and their computational study [PDF]

open access: yesRoyal Society Open Science, 2021
Click reaction is a very fast, high yield with no by-product, biocompatible, tolerant to surrounded medium, and very specific cycloaddition reaction between azides and alkynes to form triazole.
Md. Kausar Ahmed   +2 more
doaj   +1 more source

Facile and Scalable Route to Access Rare Deoxy Amino Sugars for Nonulosonic Acid Aldolase Biosynthesis

open access: yesFrontiers in Chemistry, 2022
We presented a facile and scalable route for the synthesis of di-azido sugars via one-pot double inversion of the mono-benzoyl sugars by TBAN3 and studied the dependency pattern between solvent and protecting groups as well as the configuration of the ...
Yixuan Zhou   +3 more
doaj   +1 more source

HUISGEN AND HIS ADVENTURES IN A PLAYGROUND OF MECHANISMS AND NOVEL REACTIONS [PDF]

open access: yesQuímica Nova, 2021
The death of professor Rolf Huisgen (1920-2020) was announced on March 26th 2020, in the midst of the COVID-19 pandemic. Professor Huisgen was professor emeritus at the University of Munich in Germany, and studied in detail the mechanism of the 1,3 ...
Daniel T. G. Gonzaga   +5 more
doaj   +1 more source

Crystal structure of 6-azido-6-deoxy-1,2-O-isopropylidene-α-d-glucofuranose

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
Short syntheses to high Fsp3 index natural-product analogues such as iminosugars are of paramount importance in the investigation of their biological activities and reducing the use of protecting groups is an advantageous synthetic strategy.
Adam Wood   +3 more
doaj   +1 more source

Design, Synthesis and Biological Evaluation of Syn and Anti-like Double Warhead Quinolinones Bearing Dihydroxy Naphthalene Moiety as Epidermal Growth Factor Receptor Inhibitors with Potential Apoptotic Antiproliferative Action

open access: yesMolecules, 2022
Our investigation includes the synthesis of new naphthalene-bis-triazole-bis-quinolin-2(1H)-ones 4a–e and 7a–e via Cu-catalyzed [3 + 2] cycloadditions of 4-azidoquinolin-2(1H)-ones 3a–e with 1,5-/or 1,8-bis(prop-2-yn-1-yloxy)naphthalene (2) or (6).
Essmat M. El-Sheref   +12 more
doaj   +1 more source

The Azide-Allene Dipolar Cycloaddition: Is DFT Able to Predict Site- and Regio-Selectivity?

open access: yesMolecules, 2021
The site- and regio-selectivity of thermal, uncatalysed 1,3-dipolar cycloadditions between arylazides and mono- or tetra-substituted allenes with different electronic features have been investigated by both conceptual (reactivity indices) and ...
Giorgio Molteni, Alessandro Ponti
doaj   +1 more source

Azide-Alkyne Cycloaddition Catalyzed by a Glucose/Benedict Reagent System

open access: yesChemistry Proceedings, 2021
Benedict’s Reagent is commonly used in identifying reducing sugars through a redox process where a Cu(I) species is generated. Despite the simplicity of this reaction, this has barely been investigated as a copper (I) source for catalytic processes.
Jesús G. García Torres   +5 more
doaj   +1 more source

Simultaneous evaluation of multiple microarray surface chemistries through real-time interferometric imaging. [PDF]

open access: yes, 2020
Surface chemistry is a crucial aspect for microarray modality biosensor development. The immobilization capability of the functionalized surface is indeed a limiting factor for the final yield of the binding reaction.
Brambilla, Dario   +6 more
core   +1 more source

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