Results 11 to 20 of about 129,557 (307)

SnAr Reactions of 2,4-Diazidopyrido[3,2-d]pyrimidine and Azide-Tetrazole Equilibrium Studies of the Obtained 5-Substituted Tetrazolo[1,5-a]pyrido[2,3-e]pyrimidines

open access: yesMolecules, 2022
A straightforward method for the synthesis of 5-substituted tetrazolo[1,5-a]pyrido[2,3-e]pyrimidines from 2,4-diazidopyrido[3,2-d]pyrimidine in SnAr reactions with N-, O-, and S- nucleophiles has been developed.
Kristaps Leškovskis   +3 more
doaj   +1 more source

N-(1-azido-2-(azidomethyl)butan-2-yl)-4-methylbenzenesulfonamide

open access: yesMolbank, 2022
A new bi-triazole precursor, N-(1-azido-2-(azidomethyl)butan-2-yl)-4-methylbenzenesulfonamide, was synthesized in two steps from 2-amino-2-ethyl-1,3-propanediol, with an overall yield of 80%.
Sara Hajib   +3 more
doaj   +1 more source

Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
The structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides.
Lorenzo M. Cruz   +5 more
doaj   +1 more source

One-Pot Sequence of Staudinger/aza-Wittig/Castagnoli–Cushman Reactions Provides Facile Access to Novel Natural-like Polycyclic Ring Systems

open access: yesMolecules, 2022
Realization of the one-pot Staudinger/aza-Wittig/Castagnoli–Cushman reaction sequence for a series of azido aldehydes and homophthalic anhydrides is described. The reaction proceeded at room temperature and delivered novel polyheterocycles related to the
Rodion Lebedev   +4 more
doaj   +1 more source

Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

open access: yesNanomaterials, 2022
The current study aims to explain recent developments in the synthesis of Pb(II)-azido metal-organic coordination polymers. Coordination polymers are defined as hybrid materials encompassing metal-ion-based, organic linkers, vertices, and ligands ...
Jaber Dadashi   +4 more
doaj   +1 more source

2-(2-Azabicyclo[3.2.1]octa-3,6-dien-2-yl)-1,3-dimethoxyimidazolium hexafluoridophosphate

open access: yesIUCrData, 2016
The title salt, C12H16N3O2+·PF6−, was obtained by the dipolar cycloaddition of norbornadiene to 2-azido-1,3-dimethoxyimidazolium hexafluoridophosphate.
Simone Haslinger   +3 more
doaj   +1 more source

Chemical Activation in Azide and Nitrene Chemistry: Methyl Azide, Phenyl Azide, Naphthyl Azides, Pyridyl Azides, Benzotriazoles, and Triazolopyridines [PDF]

open access: yesAustralian Journal of Chemistry, 2013
Chemical activation (the formation of ‘hot’ molecules due to chemical reactions) is ubiquitous in flash vacuum thermolysis (FVT) reactions, and awareness of this phenomenon is indispensable when designing synthetically useful gas-phase reactions. Chemical activation is particularly prevalent in azide chemistry because the interesting singlet nitrenes ...
openaire   +4 more sources

Asymmetric Synthesis of Photophore-Containing Lactisole Derivatives to Elucidate Sweet Taste Receptors

open access: yesMolecules, 2020
Lactisole, which has a 2-phenoxy propionic acid skeleton, is well-known as an inhibitor of sweet taste receptors. We recently revealed some of the structure–activity relationships of the aromatic ring and chiral center of lactisole.
Tomoya Nakagita   +5 more
doaj   +1 more source

Synthesis of Calix[4]arene Appended Lactosylated G1 and Galacto­sylated G2 Generation Glycodendrimers using a ‘CuAAC’ Click Approach

open access: yesSynOpen, 2023
A modular and highly reliable click approach is applied for the expeditious synthesis of lactose- and galactose-coated calixarene-cored G1 and G2 generation glycodendrimers, respectively.
Sunil Kumar   +4 more
doaj   +1 more source

2D frameworks self-assembled from a hydrazone ligand and azide salts: synthesis, structures, and luminescent property

open access: yesActa Chimica Slovenica, 2017
Three metal-organic coordination polymers {[Cu(L)(N3)]·(H2O)0.25}n (1), {[Zn(L)(N3)]·(H2O)0.5}n(2)and [Cd2(L)2(N3)2(H2O)]n(3)have been synthesized from hydrazone ligand N′-(1-(pyrazin-2-yl)ethylidene)isonicotinohydrazide (HL), NaN3 and corresponding ...
Peng Wang   +4 more
doaj   +1 more source

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