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Kinetic Study of the Radical Azidation with Sulfonyl Azides*

Australian Journal of Chemistry, 2013
Rate constants for the reaction between a secondary alkyl radical and two different sulfonyl azides were determined using bimolecular competing radical reactions. The rates of azidation were determined by competition with hydrogen atom transfer from tris(trimethylsilyl)silane ((TMS)3SiH) of the 4-phenylcyclohexyl radical.
Weidner Karin, Renaud Philippe
openaire +1 more source

Azide Phosphoramidite in Direct Synthesis of Azide-Modified Oligonucleotides

Organic Letters, 2014
Azide and phosphoramidite functions were found to be compatible within one molecule and stable for months in solution kept frozen at -20 °C. An azide-carrying phosphoramidite was used for direct introduction of multiple azide modifications into synthetic oligonucleotides.
Maksim A, Fomich +6 more
openaire +2 more sources

Azide

Mutation Research/Reviews in Genetic Toxicology, 1978
A, Kleinhofs, W M, Owais, R A, Nilan
openaire +2 more sources

Chemical versatility of azide radical: journey from a transient species to synthetic accessibility in organic transformations

Chemical Society Reviews, 2022
Maniklal Shee, N D Pradeep Singh
exaly

Alkinphosphonite für sequenzielle Azid‐Azid‐Kupplungen