Results 141 to 150 of about 9,434 (258)

Selective Monoreduction of 2,4 Diazido-Dideoxy Hexoses by Hydrogenation over Lindlar Catalyst. [PDF]

J Org Chem
Wiener L, Gritsch PJ, Kaiser M, Kratena N, Gärtner P.   +4 more
europepmc   +1 more source

Chemoenzymatic Synthesis of Well‐Defined α(2,8)‐ and α(2,9)‐Linked Oligosialosides

Angewandte Chemie, EarlyView.
Well‐defined α(2,8)‐ and α(2,9)‐linked oligosialic acids of different lengths can be prepared by employing recombinant bacterial polysialyltransferases in combination with chemically modified CMP‐Neu5Ac derivatives. After transfer, a sialoside is formed bearing an artificial entity, which blocks further glycosylation.
Jelle A. Fok, Keshav Kishor, Mehman I. Bunyatov, Gerlof P. Bosman, Geert‐Jan Boons   +4 more
wiley   +1 more source

Eine Interphase mit ortsfesten Ladungen synchronisiert den Ionentransport und unterdrückt raumladungsgetriebene Ineffizienz unter räumlicher Begrenzung auf Nanoliter‐Volumina

Angewandte Chemie, EarlyView.
Die elektrochemische Energiespeicherung stößt bei extremer Miniaturisierung an fundamentale Grenzen, da Grenzflächen‐ und Raumladungseffekte dominieren. Hier stellen wir eine selektive Interphase mit ortsfesten Ladungen in einer Zwillingsrohr‐μ‐Swiss‐Roll‐Architektur vor.
Yaping Yan, Jiachen Ma, Wenlan Zhang, Hongmei Tang, Yue Li, Ruhuai Mei, Yang Huang, Daniil Karnaushenko, Dmitriy D. Karnaushenko, Yumin Luo, Kai Zhang, Oliver G. Schmidt, Minshen Zhu   +12 more
wiley   +1 more source

Molecular-Scale Analysis of Barium Azide (Ba(N₃)₂) Under High Pressure: A Synchrotron X-Ray Diffraction Study on Azide Ion Rotation and Phase Transition. [PDF]

Molecules
Wu X, Jiang W, Zhang J, Ding Y, Liu Y, Liu Y, Zhu H, Zhang J, Wang J.   +8 more
europepmc   +1 more source

Katalytischer Schwefelatomtransfer vermittelt durch einen Bis(disulfido)‐Titankomplex

Angewandte Chemie, EarlyView.
Mehrelektronentransformationen mit Titan sind aufgrund der limitierten Zugänglichkeit niedervalenter Vorstufen bislang nur unzureichend untersucht. Die Vier‐Elektronen‐Aktivierung von elementarem Schwefel durch einen Ti(IV)‐Komplex führt zu einem seltenen Bis(disulfido)‐Titankomplex, der die effiziente katalytische Synthese von Isothiocyanaten aus ...
Sebastian Samir Cremer, Peter Coburger, Corinna Czernetzki, Gabriele Hierlmeier   +3 more
wiley   +1 more source

Photocatalytic Iminyl Radical Cyclization for the Synthesis of Quinazolinones. [PDF]

J Org Chem
Usanase N, Rocha JL, Yoo JJ, Lee HJ, Spencer HA, Albotabeekh MD, Sandoval JA, Gray EE.   +7 more
europepmc   +1 more source

Harnessing the Reactivity of Sulfinate Salts With Cystine: An Umpolung Approach to Residue‐Specific Peptide Modification

Angewandte Chemie, EarlyView.
While cysteine is widely employed as a nucleophilic handle for peptide modification, the electrophilicity of the oxidized form, cystine, is rarely exploited. This study describes a mild, photochemical coupling of sulfinate salts with peptide disulfides.
Joshua M. Hammond, Esteban Suárez‐Picado, Lena von Sydow, Hanna Bruss, Laurent Knerr, Magnus Johansson, Anaïs Noisier, Lara R. Malins   +7 more
wiley   +1 more source

On-DNA Platform Molecules Based on a Diazide Scaffold II: A Compact Diazide Platform Designed for Small-Molecule Drug Discovery. [PDF]

Int J Mol Sci
Miyachi H, Koshimizu M, Suzuki M.
europepmc   +1 more source

A Lipid‐Conjugation Strategy for Intracellular Reactive Oxygen Species Control in Hepatic Cells

Angewandte Chemie, EarlyView.
A lipid conjugation strategy anchors a manganese Salen complex within phospholipid membranes, yielding stable, catalytically active liposomes. These lipid–metal assemblies efficiently degrade reactive oxygen species (ROS) and enable intracellular redox control in steatotic HepaRG cells, offering a precise route to biomimetic antioxidant design ...
Olav Vestrheim, Huichao Zhao, Anders Bodholt Nielsen, Nino Wili, Niels Chr. Nielsen, Joseph A. Lyons, Rajeshwar Prosad Mookerjee, Brigitte Städler   +7 more
wiley   +1 more source

<i>In Crystallo</i> Synthesis of a Triplet Silver Nitrene. [PDF]

J Am Chem Soc
Roychowdhury P, Sur A, Figgins MT, Dutta D, Brown LM, Demeshko S, Powers DC.   +6 more
europepmc   +1 more source