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Catalyst-free aziridination and unexpected homologation of aziridines from imines

Organic & Biomolecular Chemistry, 2010
Aziridination and unpredicted homologation reaction of N-sulfonylimines were achieved easily with a very simple, rapid and mild procedure through the use of diazomethane without the presence of any catalyst. The method represents an attractive alternative to metal-catalyzed processes.
Paula Sério, Branco   +3 more
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Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles

Chemistry – A European Journal
AbstractAsymmetric catalytic aza‐Michael‐initiated ring closure of methyleneindolinones with N‐tosyloxycarbamates has been established. The reaction using a chiral nickel complex catalyst enabled the formation of a series of spiro‐aziridine oxindoles in good yields (up to 99 %) with high stereoselectivity (up to 97 % ee, >19 : 1 dr) under mild ...
Yinhe Qu   +4 more
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Epoxides and Aziridines

ChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Albert Padwa, S. Shaun Murphree
openaire   +1 more source

An Amine‐Promoted Aziridination of Chalcones.

ChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Yu-Mei, Shen   +3 more
openaire   +2 more sources

Chemistry of Carbohydrate Aziridines

2006
Publisher Summary This chapter discusses the chemistry of carbohydrate aziridines, with emphasis being placed on surveying preparative methods and ring-opening reactions. Carbohydrate aziridines or epimines are derivatives in which an aziridine ring is fused to a pyranose or furanose ring or to an exocyclic part of a carbohydrate molecule.
Jindrich, Karban, Jirí, Kroutil
openaire   +2 more sources

Organocatalytic Asymmetric Aziridination of Enones

Angewandte Chemie International Edition, 2008
A primary amine derived from cinchona alkaloids as a salt with d-N-Boc phenylglycine (Boc = tert-butoxycarbonyl) is an efficient catalyst for the aziridination of α,β-unsaturated ketones. This method is effective with both linear and cyclic substrates, leading to chiral aziridines in high yield, with complete diastereoselectivity, and with very high ...
PESCIAIOLI, FABIO   +6 more
openaire   +2 more sources

A probable aziridine radical: mechanism of addition of aziridine to styrenes

Journal of the Chemical Society D: Chemical Communications, 1969
Strong evidence of an aziridine radical in the sodium-catalysed addition of aziridine to styrenes has been obtained.
openaire   +1 more source

Aziridines

2000
David N. Roark   +2 more
openaire   +1 more source

Synthesis of steroidal aziridines

The Journal of Organic Chemistry, 1972
R, Ikan, A, Markus, Z, Goldschmidt
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The Crystal Structure of Aziridine

Angewandte Chemie International Edition in English, 1997
Mitzel, Norbert W., Riede, J, Kiener, C
openaire   +2 more sources

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