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Mechanistic Study of the Carbonylation of Aziridines to β-Lactams: Alkylation, Solvent and Molecular NaBr and MgO Clusters Catalysts Effects. [PDF]
Jendoubi A +5 more
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Comparative Nitrene-Transfer Chemistry to Olefins Mediated by First-Row Transition Metal Catalysts Supported by a Pyridinophane Macrocycle with N4 Ligation. [PDF]
Bhatia H +6 more
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Metal-Free Aziridination of Unactivated Olefins via Transient N-Pyridinium Iminoiodinanes. [PDF]
Tan H +5 more
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Formation of Scalemic Aziridines via the Nucleophilic Opening of Aziridines
The Journal of Organic Chemistry, 1997Introduction As part of our work in the preparation of aziridineallylsilanes1 we had need of a method for the preparation of simple monosubstituted, scalemic aziridines such as 1. The preparation of scalemic aziridines has been well covered in a number of reviews.2 Two methods seemed particularly well suited for the preparation of the types of ...
Stephen C., Bergmeier, Punit P., Seth
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A Sulfonyl-Substituted Aziridine
Acta Crystallographica Section C Crystal Structure Communications, 1996In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions.
Clegg, William +4 more
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ChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
Mikio, Sasaki +2 more
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Mikio, Sasaki +2 more
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Catalyst-free aziridination and unexpected homologation of aziridines from imines
Organic & Biomolecular Chemistry, 2010Aziridination and unpredicted homologation reaction of N-sulfonylimines were achieved easily with a very simple, rapid and mild procedure through the use of diazomethane without the presence of any catalyst. The method represents an attractive alternative to metal-catalyzed processes.
Paula Sério, Branco +3 more
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Organocatalytic Asymmetric Aziridination of Enones
Angewandte Chemie International Edition, 2008A primary amine derived from cinchona alkaloids as a salt with d-N-Boc phenylglycine (Boc = tert-butoxycarbonyl) is an efficient catalyst for the aziridination of α,β-unsaturated ketones. This method is effective with both linear and cyclic substrates, leading to chiral aziridines in high yield, with complete diastereoselectivity, and with very high ...
PESCIAIOLI, FABIO +6 more
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An Amine‐Promoted Aziridination of Chalcones.
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Yu-Mei, Shen +3 more
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Chemistry of Carbohydrate Aziridines
2006Publisher Summary This chapter discusses the chemistry of carbohydrate aziridines, with emphasis being placed on surveying preparative methods and ring-opening reactions. Carbohydrate aziridines or epimines are derivatives in which an aziridine ring is fused to a pyranose or furanose ring or to an exocyclic part of a carbohydrate molecule.
Jindrich, Karban, Jirí, Kroutil
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