The reaction of α-azidochalcones with carboxylic acids has been investigated resulting in the formation of α-amido-1,3-diketones under microwave irradiation via in situ formation of 2H-azirine intermediates.
Kandasamy Rajaguru +4 more
doaj +1 more source
Manganese(I)-Catalyzed Highly Enantioselective Synthesis of Aziridine Phosphines [PDF]
Herein, we present the first catalytic asymmetric nucleophilic addition of diarylphosphines to 2H-azirines, facilitated by a chiral Mn(I) complex. This method not only provides access to novel class of derivatives of the aziridine core-a structural motif
Castiñeira Reis, Marta +3 more
core +1 more source
Aminophosphonsäuren: Synthese der α-Aminophosphonsäuren aus aliphatischen Aldazinen unter Anwendung von Diisopropylphosphit [PDF]
A new efficient synthesis of α-aminophosphonic acids from aliphatic aldazines and diisopropyl phosphite is ...
Hoffmann, Maria +2 more
core +2 more sources
Intermolecular alkyl radical addition to methyl 2-(2,6-dichlorophenyl)-2H-azirine-3-carboxylate [PDF]
The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.The present work has been supported by Fundação para a Ciência e ...
Alves, Maria José Chão +3 more
core +1 more source
Enumeration of saturated and unsaturated substituted N-heterocycles
Mathematical and computational approaches in chemistry and biochemistry fill a gap in respect to the analysis of the physicochemical features of compounds and their functionality and provide an overview of known as well as yet unknown, but hypothetically
Malycheva, Tatjana, Schuster, Stefan
core
Multistep flow synthesis of vinyl azides and their use in the copper-catalyzed huisgen-type cycloaddition under inductive-heating conditions [PDF]
The multistep flow synthesis of vinyl azides and their application in the synthesis of vinyltriazoles is reported. The synthesis relies on a stable polymer-bound equivalent of iodine azide that serves to carry out 1,2-functionalization of alkenes in a ...
Kupracz, Lukas +4 more
core +3 more sources
Copper-Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3-Substituted 2H-Azirines Using an Si-B Reagent. [PDF]
Zhao ZY, Cui M, Irran E, Oestreich M.
europepmc +1 more source
Synthesis and crystal structures of new chiral 3-amino-2H-azirines and the Pd complex of one of them. [PDF]
Linden A +4 more
europepmc +1 more source
Synthetic methods for biologically relevant organofluorine compounds [PDF]
This thesis describes novel synthetic methodologies for the synthesis of biologically relevant organofluorine compounds --Abstract, page ...
Perambuduru, Meher
core +1 more source

