Strategies for Redox Potential Regulation of Organic Molecules in Nonaqueous Redox Flow Batteries
Nonaqueous organic redox flow batteries (NAORFBs) enable high‐voltage energy storage by utilizing wide electrochemical windows and tunable organic molecules. However, mismatched redox potentials and stability trade‐offs limit their performance.
Li Wang +7 more
wiley +1 more source
Unlocking azobenzene isomerization mechanisms <i>via</i> an LLM agent-driven workflow integrating simulation, experiment, and machine learning. [PDF]
Shen Y +12 more
europepmc +1 more source
Reversible Dihydrogen Splitting and Diradical Reactivity of 1,4‐Digermabenzene‐1,4‐diide
The diradical reactivity of the 1,4‐digermabenzene‐1,4‐diide, [(ADC)Ge]2, has been demonstrated with a range of substrates. Notably, it undergoes reversible dihydrogen splitting and radical coupling with TEMPO (2,2,6,6‐tetramethylpiperidinyloxyl = RO), forming [(ADC)GeH]2 and [(ADC)Ge(OR)]2, respectively.
Falk Ebeler +5 more
wiley +1 more source
Recent Advances of Azobenzene-Based Photoresponsive Molecular Switches for Protein-Targeted Photopharmacology. [PDF]
Jiang J, Yuan X, Hu L.
europepmc +1 more source
This work presents a practical approach for formulating 4D printable inks that incorporates substantial fractions of low molecular weight mesogens. By blending low molecular weight diacrylate or monoacrylate constituents with a high molecular weight main‐chain macromer, the resulting mixture proves suitable for direct ink writing, enabling mechanical ...
Lorena Ceamanos +5 more
wiley +1 more source
We here developed a molecular tool for the optical control of UGGAA repeat RNA foci, a pathological hallmark of spinocerebellar ataxia type 31 (SCA31). The photoswitchable RNA‐binding ligand enabled reversible control of the RNA foci. UV irradiation induced the growth of the RNA foci, while subsequent visible light irradiation dissolved the structure ...
Yusuke Fujiwara +2 more
wiley +2 more sources
Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles. [PDF]
Zhang K, Oestreich M.
europepmc +1 more source
The interactive, automated scaffold‐based Constellation Plot workflow provides a high‐density visual representation of the chemical space of compound datasets with complex relationships. Chemical space analysis is extensively used in different chemistry areas, ranging from the study of natural products to drug discovery projects.
Carlos D. Ramírez‐Márquez +2 more
wiley +1 more source
Pyrazole/pyrimidine derivatives endowed with azobenzenes as dual EGFR<sup>T790M</sup> and VEGFR-2 inhibitors: anticancer, docking, synthesis, design and ADMET assessments. [PDF]
Anwer KE +8 more
europepmc +1 more source
Azobenzene‐Functionalized Ionic Liquids: Light‐Responsive Surfactants With Catalytic Potential
Surface‐active imidazolium‐based ionic liquids containing an azobenzene group exhibit different micellization properties upon photoisomerization. Applying a sulfonate tag to the azobenzene moiety profoundly affects the physicochemical behavior of both isomers in water.
Markus Hegelmann +7 more
wiley +1 more source

