Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley +2 more sources
Boron Radical Promoted Metal-Free Transformation of Nitroazobenzene into Benzotriazole. [PDF]
Chen Y +11 more
europepmc +1 more source
Light‐Modulated Humidity Sensing in Spiropyran Functionalized MoS2 Transistors
A hybrid material combining molybdenum disulfide (MoS2) and spiropyran for humidity and light responsiveness is developed. Ultraviolete (UV) irradiation tunes the wettability of MoS2 decorated by spiropyran, enhancing the humidity sensitivity. Water adsorption and photochromic doping significantly alter the optoelectronic properties of MoS2 flakes ...
Adrián Tamayo +4 more
wiley +1 more source
The excited‐state intramolecular proton transfer (ESIPT) photoswitch tpmSA, which features an oxygen−acceptor, exhibits higher photochromic contrast (ΔE*Lab>74) than its nitrogen‐acceptor Schiff base analogues (ΔE*Lab<30). Theoretical calculations indicate that tpmSA effectively suppresses GSIPT, thereby enhancing the contrast.
Yahui Chen +10 more
wiley +2 more sources
Molecular Design Considerations for Azobenzene Anolytes. [PDF]
Banik A +6 more
europepmc +1 more source
Molecular solar thermal energy storage (MOST) systems offer an approach to harnessing solar energy by converting, storing, and releasing it within chemical bonds. This study introduces ethynylene‐linked 1,2‐dihydro‐1,2‐azaborinines as highly promising candidates for MOST systems, exhibiting exceptional energy densities and extended storage times.
Ralf Einholz +3 more
wiley +1 more source
Functionalized azobenzenes for micellar solar thermal energy storage as a next-generation MOST system. [PDF]
Huang R +6 more
europepmc +1 more source
Diversity of 3-chloroaniline and 3,4-dichloroaniline degrading bacteria isolated from three different soils and involvement of their plasmids in chloroaniline degradation. [PDF]
CRUL, Katrien +7 more
core +2 more sources
Struktureller Mechanismus eines Aktivitäts‐Photoschalters am β2‐adrenergen Rezeptor
Zeitaufgelöste Strukturen aus Messungen an Röntgen‐Freie‐Elektronen‐Lasern in Kombination mit zellulären Assays zeigen, wie der photoschaltbare β‐Blocker Photoazolol‐1 als Wirksamkeits‐Photoschalter der Funktion des β2‐adrenergen Rezeptor wirkt. Die lichtinduzierte Neupositionierung des Liganden verschiebt die Aktivität von inversem Agonistimus hin zu ...
Robin Stipp +29 more
wiley +1 more source
A Platform for the Development of Highly Red-Shifted Azobenzene-Based Optical Tools. [PDF]
Lützel K +17 more
europepmc +1 more source

