Results 121 to 130 of about 25,436 (256)

1,2‐Diaza‐1,3‐Dienes as a Multifaceted Synthons for the Synthesis of Heterocycles: A Fifteen‐Years Update

open access: yesEuropean Journal of Organic Chemistry, Volume 27, Issue 44, November 25, 2024.
1,2‐Diaza‐1,3‐butadienes, also called azoalkenes, have received considerable attention as key synthons for constructing various heterocyclic scaffolds. This minireview summarizes the contribution of our group in this field over the period from 2009 to the present, focusing on the role of the azoene building block in forming the heterocyclic structures.
Lucia De Crescentini   +4 more
wiley   +1 more source

Photocatalyst‐Free Wavelength‐Dependant Sequential Ring Transformations of Pyrazolo[1,2‐a]pyrazolones

open access: yesAdvanced Synthesis &Catalysis, Volume 366, Issue 21, Page 4441-4451, November 5, 2024.
Abstract We report sequential wavelength‐selective photochemical transformations of 1‐alkenylpyrazolo[1,2‐a]pyrazolones to pyrazolo[1,2‐a][1,2]diazepines or cyclobuta[c]pyrazolo[1,2‐a]pyrazolones. Irradiation of 1‐alkenylpyrazolo[1,2‐a]pyrazolones with visible‐light (blue LED, 457 nm) induced selective ‘ring switching’ transformation into pyrazolo[1,2 ...
Ines Kulašić   +5 more
wiley   +1 more source

Amino Acid Degradations Produced by Lipid Oxidation Products [PDF]

open access: yes, 2017
Differently to amino acid degradations produced by carbohydrate-derived reactive carbonyls, amino acid degradations produced by lipid oxidation products are lesser known in spite of being lipid oxidation a major source of reactive carbonyls in food. This
Hidalgo, Francisco J., Zamora, Rosario
core   +1 more source

Phosphoramidite-Cu(OTf)2 complexes as chiral catalysts for 1,3-dipolar cycloaddition of iminoesters and nitroalkenes [PDF]

open access: yes, 2013
Chiral complexes formed by phosphoramidites such as (Sa,R,R)-9 and Cu(OTf)2 are excellent catalysts for the general 1,3-dipolar cycloaddition between azomethine ylides and nitroalkenes affording the corresponding tetrasubstituted proline esters mainly as
Castelló Moncayo, Luis Miguel   +5 more
core   +2 more sources

The regioselective synthesis of spirooxindolo pyrrolidines and pyrrolizidines via three-component reactions of acrylamides and aroylacrylic acids with isatins and α-amino acids

open access: yesBeilstein Journal of Organic Chemistry, 2014
The regioselective three-component condensation of azomethine ylides derived from isatins and α-amino acids with acrylamides or aroylacrylic acids as dipolarophiles has been realized through a one-pot 1,3-dipolar cycloaddition protocol.
Tatyana L. Pavlovskaya   +6 more
doaj   +1 more source

Synthesis of Dihydrouracils Spiro-Fused to Pyrrolidines: Druglike Molecules Based on the 2-Arylethyl Amine Scaffold

open access: yesMolecules, 2010
The synthesis of a small library of dihydrouracils spiro-fused to pyrrolidines is described. These compounds are synthesized from b-aryl pyrrolidines, providing products with the 2-arylethyl amine moiety, a structural feature often encountered in ...
Daniel Blanco-Ania   +5 more
doaj   +1 more source

Synthesis of the tetracyclic core of daphnilactone B-type and yuzurimine-type alkaloid [PDF]

open access: yes, 2011
: The core of daphnilactone B-type and yuzurimine-type alkaloids was synthesized in only 16 steps from a known β-allyl-γ-butyrolactone. The key sequence of Vilsmeier–Haack cyclization and intramolecular azomethine ylide cycloaddition allowed the ...
Boudreault, Jonathan   +2 more
core   +1 more source

Binap-silver-catalyzed enantioselective multicomponent 1,3-dipolar cycloaddition of azomethines ylides derived from ethyl glyoxylate [PDF]

open access: yes, 2015
The enantioselective binap–silver catalyzed multicomponent 1,3-dipolar cycloaddition using ethyl glyoxylate, phenylalanine ethyl ester, and maleimides is described. The employment of basic silver carbonate allows the reaction to take place in the absence
Mancebo Aracil, Juan   +2 more
core   +2 more sources

One pot synthesis of pyrrolidines type 3,7-diazabicyclo [3.3.0] octane and biological activity [PDF]

open access: yes, 2008
Pyrrolidines type 2,4-disubstituted (alkyl, aryl or heteroaryl)-6,8-dioxo-3,7-diazabicyclo [3.3.0] octanes (8a-d) were successfully synthesized by an efficient one pot 1,3-dipolar cycloaddition of azomethine ylides (in situ generated from the reaction of
Amornraksa, Kitti   +2 more
core  

Addition of azomethine ylides to carbon-encapsulated iron nanoparticles

open access: yesDalton Transactions, 2018
Carbon-encapsulated iron nanoparticles have been covalently functionalized using the Prato reaction.
Artur Kasprzak   +6 more
openaire   +4 more sources

Home - About - Disclaimer - Privacy