Results 101 to 110 of about 4,540 (259)

Multicomponent Biginelli's synthesis of 3,4-dihydropyrimidin-2(1H)-ones promoted by SnCl2.2H2O

open access: yesJournal of the Brazilian Chemical Society, 2004
The ability of SnCl2.2H2O as catalyst to promote the Biginelli three-component condensation reaction from a diversity of aromatic aldehydes, ethyl acetoacetate and urea or thiourea is described.
Russowsky Dennis   +5 more
doaj  

Synthesis of bioactive heterocycles using reusable heterogeneous catalyst HClO4–SiO2 under solvent-free conditions

open access: yesGreen Chemistry Letters and Reviews, 2018
We are reporting a simple, efficient and green protocol for the synthesis of chromenes and dihydropyrimidines (products of Knoevenagel and Biginelli reaction, respectively) by the use of silica-supported perchloric acid (HClO4–SiO2) as an effective ...
Leimajam Vartima Chanu   +3 more
doaj   +1 more source

Highly Efficient Synthesis of Substituted 3,4-Dihydropyrimidin-2-(1H)-ones (DHPMs) Catalyzed by Hf(OTf)4: Mechanistic Insights into Reaction Pathways under Metal Lewis Acid Catalysis and Solvent-Free Conditions

open access: yesMolecules, 2019
In our studies on the catalytic activity of Group IVB transition metal Lewis acids, Hf(OTf)4 was identified as a highly potent catalyst for „one-pot, three-component„ Biginelli reaction.
Rui Kong   +6 more
doaj   +1 more source

Chemoselective Protection and Deprotection of Aldehydes Using Solid Supported Reagent (Silica Chloride) under Solvent-Free Conditions [PDF]

open access: yes, 2011
Silica chloride, a heterogeneous catalyst, has been found to be an efficient catalyst for the protection of aldehydes as acylals under solvent-free conditions, and deprotection of acylals to aldehydes in methanol as a solvent occurred. The reaction takes
Banditadatta, ., Pasha, M.A.
core   +1 more source

Biomimetic Chiral Nanomaterials with Selective Catalysis Activity

open access: yesAdvanced Science, Volume 11, Issue 23, June 19, 2024.
In this work, chiral nanomaterials synthesis, composition, and catalytic performances of different biochemical hybrid chiral nanomaterials are discussed. The construction of chiral nanomaterials with multiscale chiral geometries along with the underlying principles for enhancing chiroptical responses are highlighted.
Honghui Cao   +4 more
wiley   +1 more source

Sustainable Biginelli chemistry: Indian contributions to green multicomponent synthesis

open access: yesDiscover Chemistry
The Biginelli Reaction is a one-pot acid-catalysed cyclo-condensation procedure that combines urea, β-ketoester, and aromatic aldehydes to create functionalised DHPMs. For more than a century, this three-component reaction has been recognised as a method
Rajni   +4 more
doaj   +1 more source

Methyl 6-Methyl-1-(4-methylphenyl)-2-oxo-4-phenyl-1,2,3,4-tetrahydropyrimidine-5-carboxylate

open access: yesMolbank, 2012
Methyl 6-methyl-1-(4-methylphenyl)-2-oxo-4-phenyl-1,2,3,4-tetrahydro-pyrimidine-5-carboxylate has been synthesized via the modified Biginelli reaction from benzaldehyde, p-tolylurea, and methyl acetoacetate, promoted with microwave irradiation and ...
Haiping Wang, Qing Chen, Qingjian Liu
doaj   +1 more source

A modular, one-pot, four-component synthesis of polysubstituted 1,3-oxazolidines [PDF]

open access: yes, 2005
4 pages, 1 figure, 1 table, 1 scheme.-- PMID: 15675866 [PubMed].-- Printed version published Feb 4, 2005.Supporting information available: Spectroscopic and analytical data for compounds 3c-j.-- Available at: http://pubs.acs.org/doi/suppl/10.1021 ...
García-Tellado, Fernando   +4 more
core   +1 more source

SPECIFIC “IONIC LIQUIDS” AS NEW ORGANOCATALYSTS OF BIGINELLI REACTION [PDF]

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2008
New ionic liquids bearing an imidazolium core with a carboxy group have been prepared in an attempt to design new organocatalysts of Biginelli reaction. Trends in the properties of these compounds are discussed.
Viorica Sargarovschi   +2 more
doaj  

Green and Efficient Synthesis of Dihydropyrimidinone Analogues via Hpa-Clay Catalyzed Biginelli Reaction

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry
This study introduces an environmentally sustainable approach for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones (DHPMs), via the Biginelli reaction. A heterogeneous catalyst, Heteropolyacid-Clay (HPA-Clay), is developed by immobilizing H5PV2W10O40 on ...
Nuzhat Rehman   +6 more
doaj   +1 more source

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