Results 11 to 20 of about 31,276 (258)
Novel Silsesquioxane-Derived Boronate Esters—Synthesis and Thermal Properties
Molecules, 2021 The functionalization of mono- and octahydrospherosilicate with vinylboranes and allylboranes via hydrosilylation reaction in the presence of a Karstedt’s platinum (0) catalyst is presented.
Miłosz Frydrych +5 more
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Catalytic Dehydrogenation of Amine‐Boranes using Geminal Phosphino‐Boranes [PDF]
Zeitschrift für anorganische und allgemeine Chemie, 2020 The reaction of the intramolecular frustrated Lewis pair (FLP) tBu2PCH2BPh2 with the amine‐boranes NH3·BH3 and Me2NH·BH3 leads to the formation of the corresponding FLP‐H2 adducts as well as novel five‐membered heterocycles that result from capturing the in situ formed amino‐borane by a second equivalent of FLP.
Boom, D.H.A. +6 more
openaire +3 more sources
Energies, 2021 Chemical hydrogen storage stands as a promising option to conventional storage methods. There are numerous hydrogen carrier molecules that afford satisfactory hydrogen capacity.
Miriam Navlani-García +2 more
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Transformation of struvite from wastewater to a hydrogen fuel storage compound ammonia borane
Frontiers in Chemistry, 2023 Ammonia borane (NH3BH3) is a carrier of hydrogen gas that is known as a carbon-free renewable energy source. A high hydrogen content of ammonia borane and its stability in air at ambient temperatures make it a valuable molecule for its potential use as a
Nin Dingra +4 more
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Spontaneous dehydrocoupling in peri-substituted phosphine-borane adducts [PDF]
, 2016 This work was financially supported by the EPSRC and COST action CM1302 SIPs.Bis(borane) adducts Acenap(PiPr2·BH3)(PRH·BH3) (Acenap = acenaphthene-5,6-diyl; 4a, R = Ph; 4b, R = ferrocenyl, Fc; 4c, R = H) were synthesised by the reaction of excess H3B ...
Cordes, David Bradford +6 more
core +2 more sources
Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction
Beilstein Journal of Organic Chemistry, 2020 We have developed a catalytic synthetic method to prepare phenoxasilins. A borane-catalyzed double sila-Friedel–Crafts reaction between amino group-containing diaryl ethers and dihydrosilanes can be used to prepare a variety of phenoxasilin derivatives ...
Yafang Dong +4 more
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[1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene]triiodoborane benzene hemisolvate
IUCrData, 2020 In the title hemisolvate, C27H36BI3N2.0.5C6H6, the dihedral angles between the central heterocyclic ring and pendant benzene rings are 82.9 (8) and 88.7 (9)° and the complete benzene solvent molecule of crystallization is generated by a crystallographic ...
Frauke Schödel +2 more
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Molecules, 2020 Ring cleavage of cyclic ether substituents attached to a boron cage via an oxonium oxygen atom are amongst the most versatile methods for conjoining boron closo-cages with organic functional groups.
Mário Bakardjiev +4 more
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Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation [PDF]
, 2010 Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H_2 in less than 60 s at 25 °C.
Han, Won-Sik +9 more
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Crystal structure of borated N,N,N′,N′-tetramethyldiaminomethane
Acta Crystallographica Section E: Crystallographic Communications, 2015 In the title compound, {[(dimethylamino)methyl]dimethylamine}trihydridoboron, C5H17BN2, the tetrahedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed.
Kathrin Louven +2 more
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