Singlet Excited States of Anions with Higher Main Group Elements
, 2013 Previous studies have shown that dipole-bound excited states exist for certain small anions. However, valence excited states have been reported for some closed-shell anions, but those with singlet valence excited states have, thus far, contained a single
Fortenberry, Ryan C.
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Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst [PDF]
, 2011 The cross-metathesis of terminal olefins using a novel ruthenium catalyst results in excellent selectivity for the Z-olefin homodimer. The reaction was found to tolerate a large number of functional groups, solvents, and temperatures while maintaining ...
Endo, Koji +3 more
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Metal‐Free Covalent Organic Frameworks for Photocatalytic CO2 Reduction
ChemistryEurope, EarlyView.This review presents an environmentally sustainable strategy to address the critical issue of escalating atmospheric CO2 levels. It explores the application of metal‐free covalent organic frameworks in a photocatalytic approach, offering a green and efficient strategy for carbon dioxide reduction and contributing to climate change mitigation.
Supriti Dutta +3 more
wiley +1 more source
Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive Coupling of Carbon Monoxide [PDF]
, 2010 Structure-function studies on the role of pendent Lewis acids in the reductive coupling of CO are reported. Cationic rhenium carbonyl complexes containing zero, one, or two phosphinoborane ligands (Ph_2P(CH_2)_nB(C_8H_(14)), n=1-3) react with the ...
Bercaw, John E. +2 more
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Diastereoselective three-component synthesis of beta-amino carbonyl compounds using diazo compounds, boranes, and acyl imines under catalyst-free conditions [PDF]
, 2014 Diazo compounds, boranes, and acyl imines undergo a three-component Mannich condensation reaction under catalyst-free conditions to give the anti β-amino carbonyl compounds in high diastereoselectivity.
Luan, Yi +4 more
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Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications
ChemistryEurope, EarlyView.This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang +6 more
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Stoichiometric and Catalytic Synthesis of Alkynylphosphines
Molecules, 2012 Alkynylphosphines or their borane complexes are available either through C–P bond forming reactions or through modification of the phosphorus or the alkynyl function of various alkynyl phosphorus derivatives.
Annie-Claude Gaumont +3 more
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Establishing Indium in Frustrated Lewis Pair Chemistry: From Synthesis to Catalytic Applications
ChemistryEurope, EarlyView.Not that hard: The effects of chemical hardness of the soft FLP tBu2InCH2PtBu2 and its pyridine‐adduct tBu2In(py)CH2PtBu2 were examined in adduct formation reactions toward H2, CO2, and CS2. The frustrated Lewis pair shows catalytic activity in the reduction of CO2 with pinacolborane.
Daniel N. Heuer +6 more
wiley +1 more source
Borane–Trimethylamine Complex: A Versatile Reagent in Organic Synthesis
MoleculesBorane–trimethylamine complex (Me3N·BH3; BTM) is the most stable of the amine–borane complexes that are commercially available, and it is cost-effective.
Dario Perdicchia
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Tris(pentafluorophenyl)borane-Catalyzed Reactions Using Silanes
Molecules, 2019 The utility of an electron-deficient, air stable, and commercially available Lewis acid tris(pentafluorophenyl)borane has recently been comprehensively explored.
Taylor Hackel, Nicholas A. McGrath
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