CuI-Zeolite Catalysis for Biaryl Synthesis via Homocoupling Reactions of Phenols or Aryl Boronic Acids [PDF]
MoleculesDue to the importance of biaryls as natural products, drugs, agrochemicals, dyes, or organic electronic materials, a green alternative biaryl synthesis has been developed based on easy-to-prepare and cheap copper(I)-exchanged zeolite catalysts.
Xiaohui Di +7 more
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Acidity Constants of Boronic Acids as Simply as Possible: Experimental, Correlations, and Prediction [PDF]
MoleculesThe wide use of boronic compounds, especially boronic acids and benzoxaboroles, in virtually all fields of chemistry is related to their specific properties. The most important of them are the ability to form cyclic esters with diols and the complexation
Andrzej Sporzyński +5 more
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Australian Journal of Chemistry, 1965 The relative rates of iodinolysis of benzene-, thiophen-2-, and thiophen-3-boronic acids at 25° were found to be 1 : 700 : 104, or for thiophen-2- and thiophen-3-boronic acid 14 : 1. These values correlate reasonably well with data on protodetrimethylsilylation, and may be satisfactorily understood in terms of current molecular orbital theory.
RD Brown, AS Buchanan, AA Humffray
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Structural Requirements of 1-(2-Pyridinyl)-5-pyrazolones for Disproportionation of Boronic Acids [PDF]
Molecules, 2021 We observed an unusual formation of four-coordinate boron(III) complexes from the reaction of 1-(2-pyridinyl)-5-pyrazolone derivatives with arylboronic acids in the basic media.
Joungmo Cho +5 more
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Click Reactions and Boronic Acids: Applications, Issues, and Potential Solutions
Molecules, 2010 Boronic acids have been widely used in a wide range of organic reactions, in the preparation of sensors for carbohydrates, and as potential pharmaceutical agents.
Chaofeng Dai +3 more
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A Lewis Base Catalysis Approach for the Photoredox Activation of Boronic Acids and Esters [PDF]
Angewandte Chemie - International Edition, 2017 We report herein the use of a dual catalytic system comprising of a Lewis base catalyst such as quinuclidin-3-ol or 4- dimethylaminopyridine combined with a photoredox catalyst to generate carbon radicals from either boronic acids or esters.
Erik van der Eycken +2 more
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Cu-catalyzed decarboxylative coupling of propiolic acids with boronic acids
Tetrahedron Letters, 2013 A mild procedure of Cu-catalyzed decarboxylative cross-coupling of aryl- and alkynyl-boronic acids for construction of unsymmetrical substituted alkynes has been developed. The usage of inexpensive copper chloride as catalyst, and employing stable alkynl
Xun Li, Ning Jiao
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Which boronic acids are used most frequently for synthesis of bioactive molecules ? [PDF]
, 2023 Boronic acids are essential building blocks used for the synthesis of bioactive molecules, the generation of chemical libraries and the exploration of structure-activity relationships.
Odile, Decoret +3 more
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Applications of the Reversible Boronic Acids/Boronate Switch to Nucleic Acids
The Chemical Record, 2022 AbstractOver the last decades, boron and nucleic acids chemistries have gained a lot of attention for biological, medicinal and analytical applications. Our laboratory has a long‐standing interest in both chemistries and owing to the ability of boronic acids to react with cis‐diol function in aqueous media we developed over the years a variety of ...
Mégane Debiais +2 more
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Photocatalytic direct borylation of carboxylic acids
Nature Communications, 2022 Boronic acids are useful reagents in organic synthesis and thus methods to prepare these compounds under mild conditions are desirable. Here, the authors synthesize boronic acids via photocatalytic decarboxylation of benzoic acids followed by borylation;
Qiang Wei +8 more
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