Results 91 to 100 of about 15,688 (280)
Advanced Science, EarlyView.From passive to active ion transport: π‐conjugated heterocycles reconfigure the hydration environment and microphase morphology of p‐terphenyl‐based anion‐exchange membranes, enabling fast hydroxide transport and high‐performance water electrolysis. ABSTRACT Anion‐exchange membrane water electrolysis (AEMWE) is a promising technology for sustainable ...
Qian Wang +8 more
wiley +1 more source
Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride
Angewandte Chemie, EarlyView.Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal‐bipyramidal aluminum center is analyzed, and the coordination chemistry and Al(I)Br transfer reactivity of the complexes are presented.
Charlotte S. V. Weiß +1 more
wiley +2 more sources
Advanced Electronic Materials, EarlyView.Two series of self‐doped conjugated polyelectrolytes are synthesized from a non‐self‐dopable building block 3MEEET and a self‐dopable building‐block 3HOT−[TMA+] or 3HOT−[SO3H] enabling precise control over the degree of self‐doping, which in turn directly governs the threshold voltage (VT) in OECTs over a wide range of 700 mV.
Julian Hungenberg +7 more
wiley +1 more source
, 1900 The bromination of gold ore, in which the gold is extracted by means of Bromine in water, under local conditions --page ...
Tayman, Francis Joseph +1 more
core +1 more source
Flavin Catalysts in Organic Synthesis
Angewandte Chemie, EarlyView.Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +2 more sources
Low and high temperature bromination of exocyclic dienes: high temperature bromination. Part 16
, 2003 The electrophilic addition of bromine to an exocyclic diene, 5,6-dimethylenebicyclo[2.2.1]hept-2-ene, in CCl4 at 0degreesC led to the formation of non-rearranged (73%) and rearranged products (27%).
Azizoglu, A +4 more
core +1 more source
Advanced Energy Materials, EarlyView.Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor +7 more
wiley +1 more source
Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes
Angewandte Chemie, EarlyView.A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni +6 more
wiley +2 more sources
Advanced Energy Materials, EarlyView.Light‐induced halide segregation limits the stability of mixed‐halide perovskites. This perspective shows how different mechanistic models can be viewed within a common free‐energy framework. It highlights the need to separate kinetic and thermodynamic aspects, the need for bulk‐sensitive measurements, and the need for controlled conditions to identify
Markus Griesbach +3 more
wiley +1 more source
Angewandte Chemie, EarlyView.Electrocatalytic polarity inversion of azlactones unlocks their coupling with electron‐rich reaction partners. Triarylamine‐mediated oxidation of the azlactone enolate generates an electrophilic radical intermediate that undergoes selective C4 functionalization with diverse SOMOphiles.
Paula Rodríguez +6 more
wiley +2 more sources