Results 121 to 130 of about 19,520 (191)

Regio‐ and Chemoselective Palladium‐Catalyzed Additive‐Free Direct C─H Functionalization of Heterocycles with Chloroaryl Triflates Using Pyrazole‐Alkyl Phosphine Ligands

open access: yesAdvanced Science
A series of new pyrazole‐alkyl phosphine ligands with varying cycloalkyl ring sizes that enable additive‐free regio‐ and chemoselective C─H arylation of heterocycles are reported.
Changxue Gu, Chau Ming So
doaj   +1 more source

Palladium-Catalyzed C(sp3)-H Arylation of Benzo[b]thiophen-3(2H)-one 1,1-Dioxide

open access: yesJournal of Chemistry, 2019
A new concise synthesis route of 2-phenylbenzo[b]thiophen-3(2H)-one 1,1-dioxide from benzo[b]thiophen-3(2H)-one 1,1-dioxide was developed using palladium-catalyzed C(sp3)-H arylation.
Hailong Liu   +5 more
doaj   +1 more source

Understanding the Interplay Between Thermal Activation, Diffusion, and Phase Segregation of Molecular Dopants Blended with Polymeric Semiconductors

open access: yesAdvanced Electronic Materials, Volume 12, Issue 6, 23 March 2026.
The use of air stable but thermally labile molecules provides an efficient strategy for the N‐type doping of organic semiconductors with relatively low electron affinities. Design criteria for efficient dopants should also take into account diffusion and phase segregation that cannot be decoupled from thermally activated doping.
Francesca Pallini   +15 more
wiley   +1 more source

Aryl Viologen Polymers in High‐Voltage Full‐Organic Batteries

open access: yesAdvanced Energy and Sustainability Research, Volume 7, Issue 3, March 2026.
A series of aryl‐viologen polymers is synthesized, and their performance in battery half‐cells is investigated. Pairing the best‐performing polymer with a phenothiazine‐polymer positive electrode creates a full‐organic battery with a high discharge voltage of up to 1.8 V and a specific discharge capacity of 78 mAh g−1.
Philipp Penert   +4 more
wiley   +1 more source

Radical Retrosynthesis of Natural Products Enabled by Iron‐Based Reductive Olefin Coupling

open access: yesAngewandte Chemie Novit, Volume 2, Issue 1, March 2026.
This review highlights iron‐catalyzed reductive olefin coupling (ROC)—a strategy for C─C bond formation driven by metal‐hydride hydrogen atom transfer (MHAT)—as a key tool in natural products synthesis. This review surveys dozens of total syntheses employing ROC‐based strategies, highlighting its power to forge strained rings, quaternary centers, and ...
Griffin L. Barnes   +2 more
wiley   +1 more source

Stereoselective β‐C‐aryl Glycosylation Through Ni‐Catalyzed Reductive Cross‐Coupling

open access: yesChemistryEurope, Volume 4, Issue 3, March 2026.
A robust Ni‐catalyzed reductive cross‐coupling of glycosyl halides and aryl halides was developed out‐of‐the‐glovebox using air‐stable, bench‐ready Ni(COD)DQ as a source of Ni0. The reaction was applied to a broad substrate scope with excellent β‐stereoselectivity, and the obtained results are supported by mechanistic and density functional theory ...
Victor Crespin   +7 more
wiley   +1 more source

Green Synthesis of Metal Oxide Nanoparticles Using Plant Extracts: Applications in Catalysis and Biomedicine

open access: yesNano Select, Volume 7, Issue 3, March 2026.
ABSTRACT The green synthesis of metal oxide nanoparticles (MONPs) using plant‐based resources has gained significant traction as an environmentally benign, cost‐effective, and scalable alternative to traditional chemical and physical methods. This review comprehensively explores the plant‐mediated synthesis routes for a variety of MONPs, including CuO,
Faith Mwangi, Jannatun Zia, Ufana Riaz
wiley   +1 more source

Palladium-Catalyzed β-C(sp3)–H Bond Arylation of Tertiary Aldehydes Facilitated by 2-Pyridone Ligands

open access: yesMolecules
2-Pyridone ligand-facilitated palladium-catalyzed direct C–H bond functionalization via the transient directing group strategy has become an attractive topic.
Ziting Xu   +4 more
doaj   +1 more source

Palladium-Catalyzed para-C-H Arylation of Anilines with Aromatic Halides. [PDF]

open access: yesAngew Chem Int Ed Engl, 2022
Lichte D   +6 more
europepmc   +1 more source

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