Results 91 to 100 of about 3,838,786 (204)

Activation of a C−H Bond in Indene by [(COD)Rh(μ_2-OH)]_2 [PDF]

, 2009
The air- and water-tolerant hydroxy-bridged rhodium dimer [(COD)Rh(μ_2-OH)]_2 cleanly activates the aliphatic C−H bond in indene to generate [(COD)Rh(η^3-indenyl)].
Bercaw, John E., Hazari, Nilay, Labinger, Jay A.   +2 more
core   +1 more source

Transition state energy decomposition study of acetate-assisted and internal electrophilic substitution C−H bond activation by (acac-O,O)_2Ir(X) complexes (X = CH_3COO, OH) [PDF]

, 2008
Chelate-assisted and internal electrophilic substitution type transition states were studied using a DFT-based energy decomposition method. Interaction energies for benzene and methane C−H bond activation by (acac-O,O)_2Ir(X) complexes (X = CH_3COO and ...
Bischof, Steven M., Ess, Daniel H., Goddard, William A., III, Oxgaard, Jonas, Periana, Roy A.   +4 more
core   +1 more source

Reactivity of [Re\u3csub\u3e2\u3c/sub\u3e(CO)\u3csub\u3e8\u3c/sub\u3e(MeCN)\u3csub\u3e2\u3c/sub\u3e] with Thiazoles: Hydrido Bridged Dirhenium Compounds Bearing Thiazoles in Different Coordination Modes [PDF]

, 2007
Reactions of the labile compound [Re2(CO)8(MeCN)2] with thiazole and 4-methylthiazole in refluxing benzene afforded the new compounds [Re2(CO)7{μ-2,3-η2-C3H(R)NS}{η1-NC3H2(4-R)S}(μ-H)] (1, R = H; 2, R = CH3), [Re2(CO)6{μ-2,3-η2-C3H(R)NS}{η1-NC3H2(4-R)S}2(
Ahmed, Faruque, Bennett, Dennis W., Das, Anamika, Hassan, Mohammad R., Haworth, Daniel T., Hossain, G. M. Golzar, Kabir, Shariff E., Lindeman, Sergey V., Siddiquee, Tasneem   +8 more
core   +1 more source

C―H Activation [PDF]

Acta Physico-Chimica Sinica, 2019
openaire   +1 more source

Activation of H-H, C-H, C-C, and C-Cl bonds by Pd(0). Insight from the activation strain model [PDF]

, 2004
Bickelhaupt, F.M., Diefenbach, A.
core   +3 more sources

C–H Functionalization/activation in organic synthesis

Beilstein Journal of Organic Chemistry, 2016
Richmond Sarpong
doaj   +1 more source

Site-selective arylations of nature-inspired flavonoids or steroidal phenols via C—H or O—H activation

Journal of Enzyme Inhibition and Medicinal Chemistry
Phenols are important structural elements of natural products and pharmaceuticals. Due to their versatile chemical transformability, phenols are frequently used building blocks in medicinal chemistry.
Rebeka Ignácz, Noémi Bózsity, Dénes Unger, Zoltán Kele, István Zupkó, Attila Hunyadi, Marija Gjorgoska, Tea Lanišnik Rižner, Erzsébet Mernyák   +8 more
doaj   +1 more source

Iron(III)-catalyzed activation of C(sp2)-H and C(sp3)-H bonds for H/D exchange of arenes

Nature Communications
Iron-catalyzed C-H activation reactions via organometallic Fe-C intermediates have been extensively studied during the past two decades. One issue remains to be clarified is whether iron(III) salts containing weakly coordinating anions could directly ...
Chang Zheng, Yu Tang, Biao Yu
doaj   +1 more source

Iron tris-mesityl: a homoleptic iron(ii) ferrate species for directed C-H activation. [PDF]

Chem Sci
Radović A, Healy MC, Datta A, Das D, Cai L, Diaz S, Gogoi AR, Wolford NJ, Carpenter SH, Brenessel WW, McCamant D, Gutierrez O, Neidig ML.   +12 more
europepmc   +1 more source

Correction: Iron tris-mesityl: a homoleptic iron(ii) ferrate species for directed C-H activation. [PDF]

Chem Sci
Radović A, Healy MC, Datta A, Das D, Cai L, Diaz S, Gogoi AR, Wolford NJ, Carpenter SH, Brenessel WW, McCamant D, Gutierrez O, Neidig ML.   +12 more
europepmc   +1 more source