Results 61 to 70 of about 3,688 (211)

Carboranes as Lewis Acids: Tetrel Bonding in CB₁₁H₁₁ Carbonium Ylide

Crystals, 2021
High-level quantum-chemical computations (G4MP2) are carried out in the study of complexes featuring tetrel bonding between the carbon atom in the carbenoid CB11H11—obtained by hydride removal in the C-H bond of the known closo-monocarbadodecaborate ...
Maxime Ferrer, Ibon Alkorta, José Elguero, Josep M. Oliva-Enrich   +3 more
doaj   +1 more source

Molecular recognition on acoustic wave devices [PDF]

, 1992
Microporous thin films composed either of zeolite crystals embedded in sol-gel derived glass or of a molecular coupling layer, zeolite crystals and a porous silica overlayer, were formed on the gold electrodes of Quartz Crystal Microbalances (QCM). The
Bein, Thomas, Brinker, Jeffrey, Brown, Kelly D., Forrister, Ray, Yan, Yongan   +4 more
core   +1 more source

N,O-Type Carborane-Based Materials

Crystals, 2016
This review summarizes the synthesis and coordination chemistry of a series of carboranyl ligands containing N,O donors. Such carborane-based ligands are scarcely reported in the literature when compared to other heteroatom-containing donors.
José Giner Planas, Francesc Teixidor, Clara Viñas   +2 more
doaj   +1 more source

A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules

Nature Communications, 2020
The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters.
Wei Lu, Dinh Cao Huan Do, Rei Kinjo
doaj   +1 more source

Chelating N-heterocyclic carbene-carboranes offer flexible ligand coordination to IrIII, RhIII and RuII: effect of ligand cyclometallation in catalytic transfer hydrogenation [PDF]

, 2016
Imidazolium salts linked by an ethyl tether to closo-dicarbadodecaboranes were reacted with [IrCp*Cl2]2, [RhCp*Cl2]2 or [Ru(p-cymene)Cl2]2 in the presence of Ag2O to prepare complexes of the type [MCp*(NHC)Cl2] (M = Ir, Rh; NHC = N-heterocyclic carbene ...
Aher, Alberto, Altenhoff, Arnold, Arnold, Asay, Bartoszewicz, Bennett, Cavell, Charlotte E. Willans, Christopher M. Pask, Corberán, Corberán, Cross, Cross, César, El-Hellani, Estrada, Fey, Fisher, Gade, Glorius, Grafstein, Haack, Hanasaka, Hanasaka, Holmes, Hopkinson, Iglesias, Jordan Holmes, Kaufhold, Lake, Lake, Larsen, Liddle, Liu, Lv, McAnaw, Mercs, Mohamed, Mohamed, Ohara, Peng, Schaeffer, Scott, Tulloch, Van Veldhuizen, Wang, White, Wright, Wylie, Wylie, Yao, Zhang, Zhu   +54 more
core   +1 more source

Operational stability of mixed Sn–Pb perovskite solar cells: Mechanisms, mitigation strategies, and perspectives

Bulletin of the Korean Chemical Society, EarlyView.
This review consolidates mechanisms and solutions for mixed Sn–Pb perovskite solar cells. It identifies Sn2+ oxidation, iodine generation, and interfacial defects as primary instabilities. It discusses progress in additives, interface passivation, alternative hole transport layers, and solvent engineering as well as future directions for achieving long‐
Lei Chen, Kai Zhu
wiley   +1 more source

Experimental Observation of Surface Charge Inversion in a Biological Nanopore in Presence of Monovalent and Multivalent Cations [PDF]

, 2014
Surface CD133 and EpCAM, proliferation and invasiveness in breast derived cell lines. In A, representative cytofluorimetrical evaluation of CD133 and EpCAM surface levels in MCF7 and MDA-MB-468 cells after labelling with a PE-conjugated anti-CD133 ...
Federica Brugnoli (4412005), Federica Vezzali (4412008), Marco Marchisio (333289), Paola Lanuti (456018), Silvano Capitani (4411993), Silvia Grassilli (4412002), Valeria Bertagnolo (4411996), Yasamin Al-Qassab (4411999)   +7 more
core   +3 more sources

Atomically precise metal cluster enzymes for pathological tissue regeneration

BMEMat, EarlyView.
Schematic illustration of atomically precise metal cluster enzymes (MCEs) for pathological tissue regeneration. Atomically precise MCEs can modulate biological processes, such as attenuation of inflammatory responses, eradication of bacterial pathogens, regulation of angiogenesis, and promotion of cell development.
Ziqiang Xiong, Zhifeng Shi, Mengqing Li, Jien Han, Haoyan Chen, Maofei Ran, Shaojian Zhong, Limin Ma, Chengyun Ning, Youzhun Fan, Zhenghua Tang, Peng Yu   +11 more
wiley   +1 more source

Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation

Molecules, 2020
Aromatic heterocycles are ubiquitous building blocks in bioactive natural products, pharmaceutical and agrochemical industries. Accordingly, the carborane-fused heterocycles would be potential candidates in drug discovery, nanomaterials ...
Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, Ji Wu, Xin-Yu Wen, Wen-Jun Jiang, Mao Chen, Junxiao Yang   +7 more
doaj   +1 more source

Boron Neutron Capture Therapy at a Crossroads: Translational Gap and Emerging Delivery Agents

Chemistry – A European Journal, EarlyView.
This review surveys recent advances in boron delivery agents for BNCT, emphasizing the shift from classical small molecules to multifunctional nanocarriers and theranostic systems. By integrating targeting, imaging, and therapy, next‐generation boron compounds aim to bridge the gap between (bio)chemical innovation and clinical translation.
Christoph Selg, Evamarie Hey‐Hawkins
wiley   +1 more source