Chiral 1H NMR of Atropisomeric Quinazolinones With Enantiopure Phosphoric Acids [PDF]
Frontiers in Chemistry, 2018 A chiral phosphoric acid promoted enantioselective NMR analysis of atropisomeric quinazolinones was described, in which a variety of racemic arylquinazolinones such as afloqualone and IC-87114 were well recognized with up to 0. 21 ppm ΔΔδ value.
Chaofei Wu +5 more
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Phosphoric acid-catalyzed atroposelective construction of axially chiral arylpyrroles [PDF]
Nature Communications, 2019 Axially chiral arylpyrroles are structural motifs often found in natural and medicinal products. Here, the authors report the atroposelective synthesis of axially chiral arylpyrrole derivatives, which proved to be efficient chiral ligands for asymmetric ...
Lei Zhang +5 more
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Chiral phosphoric acid catalyzed aminative dearomatization of α-naphthols/Michael addition sequence [PDF]
Nature Communications, 2019 Catalytic asymmetric dearomatization (CADA) reactions readily convert common aromatic compounds to diverse 3D chiral, polycyclic molecules. Here, the authors report an intermolecular asymmetric dearomatization of nucleophile-tethered α-naphthols ...
Zi-Lei Xia +3 more
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Chiral phosphoric acid and its applications of asymmetric catalytic hydrogenation [PDF]
E3S Web of Conferences, 2021 As an excellent representative of organic small molecular catalysts, chiral phosphoric acid played an important role in asymmetric catalytic hydrogenation.
Zhuoxin Sun
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Thermal Curing-Enhanced Circularly Polarized Phosphorescence [PDF]
MoleculesDeveloping circularly polarized phosphorescence (CPP) materials integrating long-afterglow room-temperature phosphorescence (RTP) and chiral optical properties is highly attractive but challenging.
Shouchang Jiao +3 more
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Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design [PDF]
Angewandte Chemie - International Edition, 2022 Meng Duan, Xiangyang Chen, Peiyuan Yu
exaly +2 more sources
Chiral Phosphoric Acid Catalyzed Peroxidation of Imines [PDF]
Angewandte Chemie International Edition, 2010 Peroxide-containing compounds are a class of biologically important targets, many of which possess antitumor, anti-bacterial, and antimalarial activities.[1] For example, the peroxide-containing natural product artemisinin (qinghaosu) has been shown to be a highly effective antimalarial drug.[2] The chiral peroxide moiety in this natural product was ...
Wenhua, Zheng +2 more
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Recent applications of chiral phosphoric acids in palladium catalysis [PDF]
Organic & Biomolecular Chemistry, 2020 A variety of catalytic asymmetric reactions have been realized during the past decade through the combined action of palladium and chiral phosphoric acids (CPAs). This review surveys key examples and examines the underlying mechanisms of stereoinduction.
Van T. Tran +3 more
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Nature Communications, 2022 There is great interest in methods for catalytic enantioselective construction of axially chiral compounds found in natural products. Here, the authors develop a cycloaddition strategy for atroposelective construction of indole-based biaryls via chiral ...
Hui Yang +8 more
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Stereoselective Synthesis of Axially Chiral Allenes and Styrenes via Chiral Phosphoric Acid Catalysis: An Overview [PDF]
ACS OmegaAlemayehu Gashaw Woldegiorgis +5 more
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