Results 91 to 100 of about 26,308 (247)

Ladder‐Like Structural Architecture of Layered Magnetic A2.4 Cr8Te14 (A = Rb, Cs) Compounds by Self‐Flux Synthesis

open access: yesChemistry – A European Journal, EarlyView.
A2.4Cr8Te14$A_{2.4}{\rm Cr}_{8}{\rm Te}_{14}$ (A = Rb, Cs) compounds exhibit a layered, ladder‐like Cr‐Te framework uniting structural motives of hollandite‐like and delafossite‐like phases. Alkali atoms are situated both in the interlayer space and tunnels within the Cr8Te14${\rm Cr}_{8}{\rm Te}_{14}$ framework.
Kai D. Röseler   +2 more
wiley   +1 more source

α,ß-Didehydrosuberoylanilide hydroxamic acid (DDSAHA) as precursor and possible analogue of the anticancer drug SAHA

open access: yesBeilstein Journal of Organic Chemistry, 2019
An alternate synthetic route to the important anticancer drug suberoylanilide hydroxamic acid (SAHA) from its α,ß-didehydro derivative is described. The didehydro derivative is obtained through a cross metathesis reaction between a suitable terminal ...
Shital K. Chattopadhyay   +3 more
doaj   +1 more source

Mapping the potential energy surfaces for ring-closing metathesis reactions of prototypical dienes by electronic structure calculations [PDF]

open access: yes, 2011
The potential energy surfaces for ring-closing metathesis reactions of a series of simple alpha,omega-dienes which lead to 5-10 membered ring products, have been explored using density functional theory methods.
Hillier, I.H.   +3 more
core   +1 more source

Mild N‑Arylation of Sulfoximines With (Hetero)aryl Chlorides Enabled by α‐Methylnaphthyl‐tBuBrettPhos Palladium Triflate

open access: yesChemistry – A European Journal, EarlyView.
A readily accessible, air‐ and moisture‐stable palladium precatalyst, [Pd(1‐MeNAP)(tBuBrettPhos)]OTf, enables the direct N‐arylation of NH‐sulfoximines with (hetero)aryl chlorides under exceptionally mild conditions ideal for late‐stage diversification of drug‐like scaffolds.
Sourav Manna   +5 more
wiley   +1 more source

(2E,2′E)-3-(4-{[4-(4-Hydroxy-3-methoxyphenyl)but-2-en-1-yl]oxy}phenyl)-1-(2-hydroxy-4-methoxyphenyl)prop-2-en-1-one

open access: yesMolbank, 2016
A hybrid of eugenol and a chalcone has been synthesized in good yield via cross olefin metathesis. The title compound (3) was characterized by spectroscopic data including NMR, infrared, and ESI-MS.
Muhamad S. Fareza   +2 more
doaj   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

MoO3 on zeolites MCM-22, MCM-56 and 2D-MFI as catalysts for 1-octene metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2018
Highly active olefin metathesis catalysts were prepared by thermal spreading MoO3 and/or MoO2(acac)2 on MWW zeolites (MCM-22, delaminated MCM-56) and on two-dimensional MFI (all in NH4+ form).
Hynek Balcar   +3 more
doaj   +1 more source

Combining enyne metathesis with long-established organic transformations: a powerful strategy for the sustainable synthesis of bioactive molecules

open access: yesBeilstein Journal of Organic Chemistry, 2020
This account surveys the current progress on the application of intra- and intermolecular enyne metathesis as main key steps in the synthesis of challenging structural motifs and stereochemistries found in bioactive compounds.
Valerian Dragutan   +3 more
doaj   +1 more source

Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement [PDF]

open access: yes, 2009
Efficient, one-pot preparation of synthetically challenging, high molecular weight (MW), narrowly dispersed brush block copolymers and random copolymers in high conversions was achieved by ring-opening metathesis (co)polymerization (ROMP) of various ...
Grubbs, Robert H.   +3 more
core   +1 more source

Expanded Scorpionate and Siderophore‐Inspired Ligands: From Foundational Designs to Modern Applications

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley   +1 more
wiley   +1 more source

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