Results 71 to 80 of about 26,308 (247)
Light-induced olefin metathesis
Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful.
Yuval Vidavsky, N. Gabriel Lemcoff
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Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization [PDF]
Ruthenium and molybdenum catalysts are widely used in synthesis of both small molecules and macromolecules. While major developments have led to new increasingly active catalysts that have high functional group compatibility and stereoselectivity, catalyst/product separation, catalyst recycling, and/or catalyst residue/product separation remain an ...
Jakkrit Suriboot +2 more
openaire +2 more sources
Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes [PDF]
The success of enantioselective olefin metathesis relies on the design of enantioenriched alkylidene complexes capable of transferring stereochemical information from the catalyst structure to the reactants.
Dornan, Peter K. +2 more
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Seven novel Hoveyda–Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda’s precatalyst.
Etienne Borré +3 more
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A Short and Efficient Total Synthesis of Ficuseptamines A and B
A rapid and efficient total synthesis of ficuseptamines A and B by a cross metathesis strategy is described.
Hani Mutlak A. Hassan
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Designing organometallic compounds for catalysis and therapy [PDF]
Bioorganometallic chemistry is a rapidly developing area of research. In recent years organometallic compounds have provided a rich platform for the design of effective catalysts, e.g. for olefin metathesis and transfer hydrogenation.
Abraha Habtemariam +188 more
core +1 more source
Cross-metathesis reaction of α- and β-vinyl C-glycosides with alkenes
Cross-metathesis of α- and β-vinyl C-deoxyribosides and α-vinyl C-galactoside with various terminal alkenes under different conditions was studied. The cross-metathesis of the former proceeded with good yields of the corresponding products in ClCH2CH2Cl ...
Ivan Šnajdr +3 more
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Functionalized hyperbranched polymers via olefin metathesis [PDF]
Hyperbranched polymers are highly branched, three-dimensional macromolecules which are closely related to dendrimers and are typically prepared via a one-pot polycondensation of AB_(n≥2) monomers.^1 Although hyperbranched macromolecules lack the ...
Gorodetskaya, Irina A. +3 more
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Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications [PDF]
Olefin metathesis reactions with 3E-1,3-dienes using Z-selective cyclometalated ruthenium benzylidene catalysts are described. In particular, a procedure for employing 3E-1,3-dienes in Z-selective homodimerization and cross-metathesis with terminal ...
Cannon, Jeffrey S. +5 more
core +2 more sources
Ene–yne cross-metathesis with ruthenium carbene catalysts
Conjugated 1,3-dienes are important building blocks in organic and polymer chemistry. Enyne metathesis is a powerful catalytic reaction to access such structural domains.
Cédric Fischmeister, Christian Bruneau
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