Results 81 to 90 of about 4,073,254 (239)

Biobased Epoxidized Castor Oil Covalent Adaptable Networks Adhesives Reinforced with Recycled Carbon Fibers

open access: yesMacromolecular Rapid Communications, EarlyView.
It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai   +6 more
wiley   +1 more source

Multiple Olefin Metathesis Polymerization That Combines All Three Olefin Metathesis Transformations: Ring-Opening, Ring-Closing, and Cross Metathesis

open access: yes, 2016
We demonstrated tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization of monomers containing two cyclopentene moieties and postmodification via insertion polymerization.
Tae-Lim Choi (1500892)   +4 more
core   +1 more source

MoO3 on zeolites MCM-22, MCM-56 and 2D-MFI as catalysts for 1-octene metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2018
Highly active olefin metathesis catalysts were prepared by thermal spreading MoO3 and/or MoO2(acac)2 on MWW zeolites (MCM-22, delaminated MCM-56) and on two-dimensional MFI (all in NH4+ form).
Hynek Balcar   +3 more
doaj   +1 more source

Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks

open access: yesMacromolecular Rapid Communications, EarlyView.
Low‐molecular‐weight polypropylene is converted into a crosslinked polyolefin containing a covalently adaptable network. The semicrystalline material remains melt‐processable and mechanically recyclable. Its thermal and mechanical properties are comparable to commercial polyolefins.
Andrii Tiiara   +4 more
wiley   +1 more source

A convenient and efficient synthesis of (S)-lysine and (S)-arginine homologues via olefin cross-metathesis

open access: yes, 2005
A convenient five step synthesis of (S)-homolysine, incorporating a key olefin cross-metathesis step in the chain extension methodology, has been developed, together with a six step related synthesis of a new homologue of arginine, (S ...
Paul Keller (19587565)   +4 more
core  

Thiolate Salt Mediated Dynamic Silyl Ether Exchanges for Polymer Network Design and Deconstruction

open access: yesMacromolecular Rapid Communications, EarlyView.
This work introduces thiolate salts as mediators for dynamic silyl ether exchange. This platform enables the synthesis of reprocessable covalent adaptable polymer networks (CANs) and allows for sterically controlled, and tunable deconstruction of silyl ether‐containing thermosets.
Pierce T. Bombard   +9 more
wiley   +1 more source

Selective Domino Ring-Closing Metathesis−Cross-Metathesis Reactions between Enynes and Electron-Deficient Alkenes

open access: yes, 2016
A selective domino ring-closing metathesis (RCM)−cross-metathesis (CM) process between enynes and electron-deficient alkenes is reported. The conditions have been optimized for enynes 3 and methyl acrylate with catalyst IV.
Claire Vilain (3067122)   +3 more
core   +1 more source

Sulfur‐Rank‐Dependent Dispersion and Precipitation Behavior of Structurally Defined Sulfur‐Containing Polymers

open access: yesMacromolecular Rapid Communications, EarlyView.
Poly(vinylpyrrolidone) creates a quasi‐stable dispersion copolymerization system that enables direct comparison of the dispersed and precipitated polymer fractions. Structural analysis shows that fractionation correlates more strongly with sulfur rank than with molecular weight, revealing how the number of consecutive sulfur atoms in the polysulfide ...
Takumi Hashimoto   +9 more
wiley   +1 more source

Alkenol−Alkyne Cross Metathesis

open access: yes, 2016
Allyl alcohols and their homologues were used in the enyne cross metathesis to prepare hydroxy-functionalized dienes. An isomerization was found to occur under prolonged heating, and a method for conversion to (E)-diene product is also ...
Steven T. Diver (1667287)   +2 more
core   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

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