Results 171 to 180 of about 491,196 (368)

Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor [PDF]

open access: yes, 2009
The one-electron oxidation of tetramethoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially π-stacked conformer as established by (i) electrochemical analysis, (ii) by the observation of the
Chebny, Vincent J.   +3 more
core   +1 more source

One‐Pot Cascade Synthesis of Isoquinolinone‐Fused Quinoxalines Through Sequential Rh(III)/Pd(II) Catalysis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A new one‐pot, dual catalytic strategy for the synthesis of polycyclic isoquinolinone‐fused quinoxalines from commercially available N‐(2‐acetamidophenyl)benzamides and 1,3‐diynes is reported. This transformation proceeds via Rh(III)/Pd(II)‐mediated sequential NH/CH activation/annulation. Detailed mechanistic studies elucidate the reaction pathway. A
Wei‐Jung Chiu   +3 more
wiley   +1 more source

Sostenibilità e design del gioiello

open access: yesAnd
La ricerca affronta il tema del design del gioiello in un’ottica di sostenibilità ambientale e sociale relativa tanto ai materiali preziosi utilizzati quanto ai processi produttivi impiegati.
Alessandra Avella, Nicola Pisacane
doaj  

On the Role of MWCNTs for the Effective Detection of Glucose Using MWCNTs/NiO/MWCNTs Stacks on Carbon Paper Electrodes

open access: yesAdvanced Sensor Research, EarlyView.
This study deciphers the mechanism of enhanced glucose detection using multiwalled carbon nanotubes and nickel oxide stacks (MWCNTs/NiO/MWCNTs) on commercially available carbon paper electrodes. We demonstrate the role of MWCNTs where the defects enrich the electrocatalytic activity when they come in contact with the glucose molecule for its selective ...
Akshay Parab   +6 more
wiley   +1 more source

Hepatitis E Virus ORF1 Polyprotein Harbors a Pocket‐Like Cavity That Is Vital for Virus Replication and Represents a Novel Antiviral Target

open access: yesAdvanced Science, EarlyView.
Within the hepatitis E virus (HEV) ORF1 polyprotein, the X domain interacts with viral RNA‐dependent RNA polymerase (RdRp), forming a functional “pocket‐like” cavity (PC) that is crucial for viral replication. Structure‐based screening, surface plasmon resonance (SPR) assays, and HEV model validation collectively identify saikosaponin D and ...
Xiaohui Ding   +15 more
wiley   +1 more source

Structural and Functional Versatility of the Amyloidogenic Non‐Amidated Variant of the Antimicrobial Peptide Citropin 1.3

open access: yesAdvanced Science, EarlyView.
Citropin 1.3 is an antimicrobial peptide derived from amphibians that forms amyloid structures. Here, the structural and functional properties of citropin 1.3 are characterized. Using high‐resolution imaging approaches, a variety of canonical and undescribed fibril morphologies are identified.
Fabio Strati   +8 more
wiley   +1 more source

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