Photoinduced, Copper-Catalyzed Decarboxylative C–N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement [PDF]
Journal of the American Chemical Society, 2017 Wei Zhao, Ryan Ρ Wurz, Jonas C Peters
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The Curtius rearrangement: mechanistic insight and recent applications in natural product syntheses [PDF]
Organic and Biomolecular Chemistry, 2018 Arun K Ghosh +2 more
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N-Acylbenzotriazoles as Proficient Substrates for an Easy Access to Ureas, Acylureas, Carbamates, and Thiocarbamates via Curtius Rearrangement Using Diphenylphosphoryl Azide (DPPA) as Azide Donor [PDF]
Synthesis, 2021 A diverse range of ureas, N-acylureas, carbamates, and thiocarbamates has been synthesized in good to excellent yields by reacting N-acylbenzotriazoles individually with amines or amides or phenols or thiols in the presence of diphenylphosphoryl azide ...
Vinod K Tiwari
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Phys Chem Chem PhysThe Curtius and the Wolff rearrangement reactions are investigated in the gas phase by tandem mass spectrometry (MS) and infrared ion spectroscopy (IRIS), probing the nature and intrinsic reactivity of three acyl azides and of one α-diazo keto analyte ...
Harnying W +8 more
europepmc +4 more sources
Oxidative N−N Bond Formation Versus the Curtius Rearrangement [PDF]
Chemistry – A European JournalAbstractThe oxidative formation of N−N bonds from primary amides has been recently reported and then retracted in the journal Nature Communications by Kathiravan, Nicholls, and co‐authors, utilizing a hypervalent iodane reagent. Unfortunately, the authors failed to recognize the Curtius reaction taking place under the described reaction conditions ...
Melissa Hohenadel +3 more
semanticscholar +5 more sources
An efficient new method for the synthesis of 3-[18 F]fluoro-4-aminopyridine via Yamada-Curtius rearrangement. [PDF]
J Labelled Comp Radiopharm, 2018 Basuli F +4 more
europepmc +4 more sources
Azide monoliths as convenient flow reactors for efficient Curtius rearrangement reactions
Organic and Biomolecular Chemistry, 2008 The preparation and use of an azide-containing monolithic reactor is described for use in a flow chemistry device and in particular for conducting Curtius rearrangement reactions via acid chloride inputs.
Marcus Baumann +2 more
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The Curtius Rearrangement: Applications in Modern Drug Discovery and Medicinal Chemistry. [PDF]
ChemMedChem, 2018 The Curtius rearrangement is the thermal decomposition of an acyl azide derived from carboxylic acid to produce an isocyanate as the initial product. The isocyanate can undergo further reactions to provide amines and their derivatives.
Ghosh AK, Brindisi M, Sarkar A.
europepmc +2 more sources
Boc-protected 1-(3-oxocycloalkyl)ureas via a one-step Curtius rearrangement: mechanism and scope. [PDF]
Tetrahedron Lett, 2014 Sun X +5 more
europepmc +4 more sources
Pyridone Annulation via Tandem Curtius Rearrangement/6π-Electrocyclization: Total Synthesis of (−)-Lyconadin C [PDF]
Organic Letters, 2013 Xiayun Cheng, Stephen P Waters
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