Results 171 to 180 of about 8,110 (222)
Synthesis of Novel Sugar Amino Acids by Curtius Rearrangement
AbstractSugar amino acids (SAAs) bearing an amine group on the anomeric position are a challenging class of SAAs to synthesize due to the inherent instability of glycosylamines. We developed a novel synthetic strategy towards both furanoid and pyranoid δ‐SAAs of this type, based on a Curtius rearrangement. The latter reaction, which is known to proceed
Renate M. van Well+7 more
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The curtius rearrangement in aminimides (II)
Herman P. Benecke
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Curtius-rearrangement of “rigid” azides
Walter Lwowski+3 more
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Some Applications of the Curtius Rearrangement
Journal of the Chemical Society, Perkin Transactions 1, 1983Pairs of optically pure enantiomers of substituted 1,1 -diamines have been prepared from the azides of L-amino-acids via the Curtius rearrangement.This synthesis is based on the interchange of two groups attached to the asymmetrically substituted tetrahedral α-carbon atom of the parent amino acid.
Iphigenia Photaki+1 more
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Synthesis of 2,2‐[60]Fullerenoalkylamines (IV) via the Curtius Rearrangement. [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Kazuhiko Saigo+2 more
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ChemInform Abstract: Synthesis of 2‐Arylethylamines by the Curtius Rearrangement. [PDF]
AbstractNovel chemical syntheses of amphetamines (V), (VIII) and (XV) as well as wescaline (XI) using the Curtius rearrangement as key reaction are developed.
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Improved Preparation of Tyramine by Curtius Rearrangement
Chinese Journal of Chemistry, 2009AbstractAn improved and facile preparation of tyramine [2‐(p‐hydroxyphenyl)ethylamine] was described, which starts from phenol and acrylonitrile to form β‐(p‐hydroxyphenyl) propionic acid via Friedel‐Craft's alkylation and nitrile hydrolysis. After hydrazinolysis and a subsequent Curtius rearrangement, tyramine was obtained in 30.2% total yield.
Li-Xin Wang+5 more
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Curtius-type rearrangement of a sulphonyl azide
Journal of the Chemical Society D: Chemical Communications, 1969Six products have been identified from the thermolysis of mesitylene-2-sulphonyl azide in dodecane: two are derived from a Curtius-type rearrangement of the corresponding sulphonyl nitrene.
Rudolph A. Abramovitch, W. D. Holcomb
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ChemInform, 2011
AbstractThe method avoids the isolation of the potentially hazardous azide intermediate and can be scaled up as an industrial process.
Bojan P. Bondzic+3 more
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AbstractThe method avoids the isolation of the potentially hazardous azide intermediate and can be scaled up as an industrial process.
Bojan P. Bondzic+3 more
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ChemInform Abstract: The Use of Curtius Rearrangement in the Synthesis of 4‐Aminothiazolidines.
ChemInform, 1999AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Edson R. Costenaro+2 more
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