Results 21 to 30 of about 3,572,666 (356)

Efficient Synthesis of Isoquinoline Derivatives through Sequential Cyclization–Deoxygenation Reaction of 2-Alkynylbenzaldoximes

SynOpen, 2022
We describe a novel, simple, robust, and efficient cyclization/deoxygenation approach for the synthesis of functionalized isoquinoline derivatives. Over the course of continued studies on o-alkynylbenzaldoxime cyclization reactions, the formation of ...
Mojtaba Ayoubi, Ali Nikbakht, Kamran Amiri, Alireza Abbasi Kejani, Hossein Zahedian Tejeneki, Saeed Balalaie   +5 more
doaj   +1 more source

Cannabidiol as the Substrate in Acid-Catalyzed Intramolecular Cyclization

Journal of Natural Products, 2020
The chemical reactivity of cannabidiol is based on its ability to undergo intramolecular cyclization driven by the addition of a phenolic group to one of its two double bonds.
Paola Marzullo, Francesca Foschi, David Coppini, Fabiola Fanchini, L. Magnani, S. Rusconi, M. Luzzani, D. Passarella   +7 more
semanticscholar   +1 more source

Free radical 5-exo-dig cyclization as the key step in the synthesis of bis-butyrolactone natural products: experimental and theoretical studies [PDF]

, 2011
Radical cyclization reactions were performed by 5-exo-dig mode to yield cis-fused bicyclic systems, leading to the synthesis of bis-butyrolactone class of natural products.
Allinger, Baldwin, Beckwith, Beckwith, Beckwith, Blot, Cossy, Curtiss, Devoju Harinada Chary, Florian Achrainer, Gangavaram V. M. Sharma, Hendrik Zipse, Lii, Lii, Nagula Chandramouli, Sateesh Patrudu, Sharma, Sharma, Sharma, Sharma, Sharma, Sharma, Srikrishna, Yu   +23 more
core   +1 more source

Unified short syntheses of oxygenated tricyclic aromatic diterpenes by radical cyclization with a photoredox catalyst

Communications Chemistry, 2023
The biomimetic two-phase strategy employing polyene cyclization and subsequent oxidation/substitution is an effective approach for divergent syntheses of [6-6-6]-tricyclic diterpenes.
Riichi Hashimoto, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi   +3 more
doaj   +1 more source

Sequence Dependence of Transcription Factor-Mediated DNA Looping [PDF]

, 2012
DNA is subject to large deformations in a wide range of biological processes. Two key examples illustrate how such deformations influence the readout of the genetic information: the sequestering of eukaryotic genes by nucleosomes, and DNA looping in ...
Barry, Bellomy, Bellomy, Brenowitz, Butler, Chen, Chen, Cloutier, Cloutier, Drew, Du, Echols, Edelman, Finzi, Frank, Garcia, Geggier, Han, Hirsh, Hogan, Hsieh, Jacobson, Krämer, Lewis, Lowary, Luger, Luijsterburg, Martin Lindén, Matthews, Mehta, Milstein, Morgan, Müller, Newman, Normanno, Oehler, Olson, Peters, Plischke, Ptashne, Rippe, Rob Phillips, Rutkauskas, Saiz, Schafer, Schleif, Segall, Shimada, Stephanie Johnson, Swigon, Tolhuis, Towles, Vanzi, Villa, Watson, Whitson, Whitson, Widom, Wong, Xu, Yin, Zhan, Zhang   +62 more
core   +4 more sources

Photoexcitation of flavoenzymes enables a stereoselective radical cyclization

Science, 2019
Light teaches (co)enzymes new tricks Light is widely used in organic synthesis to excite electrons in a substrate or catalyst, opening up reactive pathways to a desired product.
Kyle F. Biegasiewicz, S. Cooper, Xin Gao, Daniel G. Oblinsky, J. Kim, S. Garfinkle, Leo A. Joyce, B. Sandoval, G. Scholes, T. Hyster   +9 more
semanticscholar   +1 more source

Study on by-products synthesis of powder coating polyester resin catalyzed by organotin

e-Polymers, 2023
In the production of powder-coating polyester, a strong odor emanates from the water, prompting us to investigate its composition and origin. We studied the process of powder coating epoxy/polyester 50/50, which employs butyl tin tris (2-ethyl hexanoate)
Yang YuCheng, Di Chao, Wang TingWei
doaj   +1 more source

Surface Modification of Ga-Doped-LLZO (Li₇La₃Zr₂O₁₂) by the Addition of Polyacrylonitrile for the Electrochemical Stability of Composite Solid Electrolytes

Energies, 2023
Composite solid electrolytes (CSEs), often incorporating succinonitrile (SCN), offer promi I confirm sing solutions for improving the performance of all-solid-state batteries.
Hyewoo Noh, Daeil Kim, Wooyoung Lee, Boyun Jang, Jeong Sook Ha, Ji Haeng Yu   +5 more
doaj   +1 more source

Iodoarene-Catalyzed Cyclizations of Unsaturated Amides [PDF]

, 2015
The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route.
Ali Alhalib, Bode H. B., Degnan B. M., Dohi T., Dohi T., Fujita M., Fujita M., Guilbault A.-A., Guilbault A.-A., Hamnett D. J., Kong A., Mizar P., Moon N. G., Murai T., Ngatimin M., Parra A., Richardson R. D., Rodríguez A., Rodríguez A., Shimogaki M., Somaia Kamouka, Suzuki S., Uyanik M., Uyanik M., Wesley J. Moran, Wu H., Yan J., Zhdankin V. V., Zheng Z. S., Zhong W., Zhou Z.-S.   +30 more
core   +1 more source

Asymmetric Nazarov cyclizations [PDF]

Tetrahedron, 2011
The Nazarov cyclization1 is described as the 4 π electron conrotatory cyclization of a pentadienyl cation. The past 20 years have brought resurgent interest in this reaction most likely due to the realization that it can provide rapid and efficient access to multisubstituted cyclopentenones with excellent stereochemical control at two (or even three ...
Naoyuki, Shimada, Craig, Stewart, Marcus A, Tius   +2 more
openaire   +2 more sources