Results 21 to 30 of about 56,559 (262)

Dianionic Phase-Transfer Catalyst for Asymmetric Fluoro-cyclization [PDF]

open access: yes, 2018
Inspired by the dicationic nature of the electrophilic fluorinating reagent, Selectfluor (1), we rationally designed a series of dicarboxylic acid precatalysts (2), which, when deprotonated, act as anionic phase-transfer catalysts for asymmetric ...
Yuji Kawato (1548028)   +6 more
core   +1 more source

Surface Modification of Ga-Doped-LLZO (Li7La3Zr2O12) by the Addition of Polyacrylonitrile for the Electrochemical Stability of Composite Solid Electrolytes

open access: yesEnergies, 2023
Composite solid electrolytes (CSEs), often incorporating succinonitrile (SCN), offer promi I confirm sing solutions for improving the performance of all-solid-state batteries.
Hyewoo Noh   +5 more
doaj   +1 more source

Non-native Radical Cyclization Catalyzed by a B12-Dependent Enzyme [PDF]

open access: yes, 2023
Despite the unique reactivity of vitamin B12 and its derivatives, B12-dependent enzymes remain underutilized in biocatalysis. In this study, we repurpose the B12-dependent transcription factor CarH to enable non-native radical cyclization reactions.
Jianbin, Li   +2 more
core   +1 more source

Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines

open access: yesBeilstein Journal of Organic Chemistry, 2021
A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl3-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling.
Najeh Tka   +4 more
doaj   +1 more source

Urine Metabolite Profiling of Human Colorectal Cancer by Capillary Electrophoresis Mass Spectrometry Based on MRB

open access: yesGastroenterology Research and Practice, 2012
Aim. The study was to investigate the metabolic profile of urine metabolites and to elucidate their clinical significance in patients with colorectal cancer. Methods. Colorectal cancers from early stage and advanced stage were used in this study.
Jin-Lian Chen   +6 more
doaj   +1 more source

Synthesis and Biological Activities of Pyrazino[1,2-a]indole and Pyrazino[1,2-a]indol-1-one Derivatives

open access: yesPharmaceuticals, 2021
This review concerns the synthesis and biological activities of pyrazino[1,2-a]indoles and pyrazino[1,2-a]indol-1-ones reported since 1997 and the discovery of biological activity of pyrazinoindole derivatives.
Kena Zhang   +4 more
doaj   +1 more source

CYCLIZATION AND HYDROGENATION OF (+)-CITRONELLAL TO MENTHOLS OVER ZnBr2 AND Ni CATALYSTS SUPPORTED ON γ-Al2O3

open access: yesIndonesian Journal of Chemistry, 2010
Two steps transformation of (+)-citronellal, cyclization and hydrogenation, on ZnBr2/γ-Al2O3 and Ni/γ-Al2O3 catalyst have been realized with the selectivity to cyclization products (isopulegols) was very high (yield up to ~92.58%) over ZnBr2/γ-Al2O3 ...
Elvina Dhiaul Iftitah   +3 more
doaj   +1 more source

Tailoring the squalene-hopene cyclase for stereoconvergent and efficient cationic cyclization cascades [PDF]

open access: yes, 2022
Asymmetric catalysis has witnessed paramount lessons from terpene cyclase enzymology such as the ability to control dynamic carbocations or cationic cyclization cascades.
Christian, Curado   +4 more
core   +1 more source

Biology Beyond Biochemistry:The Mechanics of Life [PDF]

open access: yes, 2005
In the last half century, biologists have made great strides towards understanding the intricate structure of the cell and the relation between this structure and cellular function.
Wiggins, Paul Alexander
core   +1 more source

Asymmetric Nazarov cyclizations [PDF]

open access: yesTetrahedron, 2011
The Nazarov cyclization1 is described as the 4 π electron conrotatory cyclization of a pentadienyl cation. The past 20 years have brought resurgent interest in this reaction most likely due to the realization that it can provide rapid and efficient access to multisubstituted cyclopentenones with excellent stereochemical control at two (or even three ...
Naoyuki, Shimada   +2 more
openaire   +2 more sources

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