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Routes to Cyclobutadiene and Cycloallyl Pt(II) Complexes: Dicationic Bis(Alkyne) Species as Intermediates

open access: yesChemistry – A European Journal, EarlyView.
This work demonstrates the synthesis of cationic Pt(II) η3‐cycloallyl complexes, and experimental and computational studies show a ligand bite‐angle dependence of their formation rates. The reactivity of these complexes with Brønsted acids was investigated, leading to the formation of cationic and dicationic Pt(II) η4‐cyclobutadiene complexes ...
Ouchan He   +6 more
wiley   +1 more source

Asymmetric Total Synthesis of (-)-Verrucarol. [PDF]

open access: yesAngew Chem Int Ed Engl
Powers MH   +5 more
europepmc   +1 more source
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Do Antarafacial Cycloadditions Occur? Cycloaddition of Heptafulvalene with Tetracyanoethylene

Chemistry – A European Journal, 2022
AbstractThe cycloaddition of heptafulvalene (1) with tetracyanoethylene (TCNE) was previously described as an example of an antarafacial cycloaddition, a [π14a+π2s] process that afforded only the trans cycloadduct by virtue of the edge‐to‐face approach of TCNE, facilitated by the S shape of 1.
Anthony R. Izzotti, James L. Gleason
openaire   +2 more sources

Advances in cycloaddition polymerizations

Chem. Soc. Rev., 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Glenn W, Goodall, Wayne, Hayes
openaire   +2 more sources

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