This work demonstrates the synthesis of cationic Pt(II) η3‐cycloallyl complexes, and experimental and computational studies show a ligand bite‐angle dependence of their formation rates. The reactivity of these complexes with Brønsted acids was investigated, leading to the formation of cationic and dicationic Pt(II) η4‐cyclobutadiene complexes ...
Ouchan He +6 more
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Asymmetric Total Synthesis of (-)-Verrucarol. [PDF]
Powers MH +5 more
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Electrochemically driven strain-release dearomative (3 + 2) cyclization for the synthesis of bicyclo[2.1.1]hexane-fused polycyclic spiroindolines. [PDF]
Zhu Y +8 more
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C3-H methylenephosphonylation of azaarenes enabled by catalyst-controlled regioselective cyclizative rearrangement. [PDF]
Liu D, Li FZ, He YP, Wu H.
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Biocatalytic Epoxidation Pathway of Oils in Sponge-Like Ionic Liquids Toward CO<sub>2</sub>-Derived Cyclic Carbonate Synthesis. [PDF]
Ruiz FJ +7 more
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Visible-light-enabled excited-state dearomatization reactions. [PDF]
Li M, Cheng YZ, You SL.
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Why is a dicationic digallene so reactive towards activation of strong covalent bonds? Scope and mechanistic investigations. [PDF]
Barthélemy A +4 more
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Do Antarafacial Cycloadditions Occur? Cycloaddition of Heptafulvalene with Tetracyanoethylene
Chemistry – A European Journal, 2022AbstractThe cycloaddition of heptafulvalene (1) with tetracyanoethylene (TCNE) was previously described as an example of an antarafacial cycloaddition, a [π14a+π2s] process that afforded only the trans cycloadduct by virtue of the edge‐to‐face approach of TCNE, facilitated by the S shape of 1.
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Advances in cycloaddition polymerizations
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