Results 211 to 220 of about 157,130 (323)
Synthetic Methods for Four-Membered Carbocycles Bearing Emerging Fluorinated Motifs. [PDF]
Yanai H +3 more
europepmc +1 more source
CuH‐Catalyzed Asymmetric Desymmetrization of Cyclobutenes via Stereodivergent Hydroamination
The CuH‐catalyzed stereodivergent hydroamination through asymmetric desymmetrization of cyclobutenes has been achieved, yielding a range of trisubstituted aminocyclobutanes with excellent results. A series of subsequent transformations, including the first asymmetric synthesis of two pharmaceutically active molecules, have been realized, and density ...
Xiang Lei +8 more
wiley +1 more source
Asymmetric [3 + 2] Cycloaddition to Access 3-Pyrrolines and Their Switchable Transformations to Nine-Membered Cyclic Sulfamidates and 2H-Pyrroles. [PDF]
Choi SM, Park JU, Kim JH.
europepmc +1 more source
Nearly identical molecular modifications of two differently shaped cuprous oxide via click chemistry lead to a striking divergence in product selectivity in CO2 electrolysis—favoring either methane or C2+ compounds. This contrast reveals dual roles of the organic layer : forming distinct functional sites that act synergistically and disrupting copper ...
Ayumu Sakamoto +8 more
wiley +1 more source
The high potential of methyl laurate as a recyclable competitor to conventional toxic solvents in [3 + 2] cycloaddition reactions. [PDF]
Yıldırım A, Göker M.
europepmc +1 more source
Diversitätsorientierte Synthese bioaktiver Allocolchicinoide und Colchicinoide unter Verwendung Übergangsmetall-katalysierter Cycloadditionen [PDF]
Nicolaus, Norman
core
A one‐pot protocol to synthesize reactive benzyl‐ and allyl‐halide‐substituted (dihydro)naphthalenes from 2,3‐aryl‐1,3‐butadiene substrates and halogenated alkanes has been developed, using [Cp*RuCl(PPh3)2] as the catalyst. Mechanistic studies revealed an atom transfer radical addition and radical benzannulation sequence, followed by HCl elimination ...
Nicole S. van Leeuwen +9 more
wiley +1 more source

