Results 211 to 220 of about 157,130 (323)

CuH‐Catalyzed Asymmetric Desymmetrization of Cyclobutenes via Stereodivergent Hydroamination

open access: yesChemistryEurope, EarlyView.
The CuH‐catalyzed stereodivergent hydroamination through asymmetric desymmetrization of cyclobutenes has been achieved, yielding a range of trisubstituted aminocyclobutanes with excellent results. A series of subsequent transformations, including the first asymmetric synthesis of two pharmaceutically active molecules, have been realized, and density ...
Xiang Lei   +8 more
wiley   +1 more source

Surface Modification via Click Chemistry Enhances CO2 Reduction Selectivity between C2+/C1 on Shape‐Controlled Cu2O

open access: yesChemistryEurope, EarlyView.
Nearly identical molecular modifications of two differently shaped cuprous oxide via click chemistry lead to a striking divergence in product selectivity in CO2 electrolysis—favoring either methane or C2+ compounds. This contrast reveals dual roles of the organic layer : forming distinct functional sites that act synergistically and disrupting copper ...
Ayumu Sakamoto   +8 more
wiley   +1 more source

Cycloaddition Reactions

open access: yesJournal of Synthetic Organic Chemistry, Japan, 1971
openaire   +2 more sources

SYNTHESE ET MODÉLISATION DE NOUVEAUX SYSTÉMES HÉTÉROCYCLIQUES OBTENUS PAR CYCLOADDITION 1 ,3- DIPOLAIRE DERIVANT DE LA 1,5-BENZODIAZÉPINE-2,4-DIONE

open access: green, 2015
R. Dardouri   +6 more
openalex   +1 more source

One‐Pot Ruthenium‐Catalyzed Synthesis of Benzyl/Allyl‐Halide Substituted (dihydro)naphthalenes via Radical Benzannulation

open access: yesChemistryEurope, EarlyView.
A one‐pot protocol to synthesize reactive benzyl‐ and allyl‐halide‐substituted (dihydro)naphthalenes from 2,3‐aryl‐1,3‐butadiene substrates and halogenated alkanes has been developed, using [Cp*RuCl(PPh3)2] as the catalyst. Mechanistic studies revealed an atom transfer radical addition and radical benzannulation sequence, followed by HCl elimination ...
Nicole S. van Leeuwen   +9 more
wiley   +1 more source

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