Results 91 to 100 of about 55,695 (341)
1,5-Induction in reactions between 2-alkoxy-(2-tributylstannylethylidene)cyclohexanes and aldehydes
Journal of the Brazilian Chemical Society, 2001 2-Methoxy(2-tributylstannylethylidene)cyclohexane 16 undergoes stereoselective transmetalation on treatment with tin(IV) chloride to generate the allyltin trichloride 19 which reacts with aldehydes to give the (Z)-(3-hydroxyalkylidene)-2 ...
Kumar Poonam +2 more
doaj
Pushing the limits of concertedness. A waltz of wandering carbocations. [PDF]
, 2019 Among the array of complex terpene-forming carbocation cyclization/rearrangement reactions, the so-called "triple shift" reactions are among the most unexpected.
Castiñeira Reis, Marta +3 more
core
Advanced Optical Materials, EarlyView.Diatomite‐based light extraction structures enable enhanced photon outcoupling through multi‐angle scattering and far‐field redistribution. By harnessing the unique scattering behavior of diatomite, this approach introduces randomly oriented scattering centers that effectively reshape internal light propagation.
Chang Min Lee +12 more
wiley +1 more source
Highly-functionalised difluorinated cyclohexane polyols via the Diels–Alder reaction : regiochemical control via the phenylsulfonyl group [PDF]
, 2005 A difluorinated dienophile underwent cycloaddition reactions with a range of furans to afford cycloadducts whichcould be processed regio- and stereoselectively via episulfonium ions, generated by the reaction between their alkenyl groups and ...
Crowley, Patrick J +5 more
core +1 more source
Advanced Optical Materials, EarlyView.In bi‐polymeric mechanochromic cantilevers composed of polydimethylsiloxane (PDMS) and off‐stoichiometry thiol‐ene‐epoxy (OSTE+), differential swelling between the two polymers in response to VOC exposure induces a competitive bidirectional bending and corresponding color changes, with three characteristic response modes related to the Hansen ...
Ferran Pujol‐Vila +2 more
wiley +1 more source
Nitromethane conjugate addition to 2-[(1E,3E)-4-arylbuta-1,3-dien-1-yl]-4Hchromen- 4-ones [PDF]
, 2017 Chromone are a group of oxygen-containing heterocycles, which are often associated to important biological activities.1 Chromone derivatives are also seen as interesting scaffolds to input further functionalizations,2 most of them through chemical ...
Albuquerque, Hélio +3 more
core +1 more source
Fluorescent sensing of maleate versus fumarate by a neutral cyclohexane based thiourea receptor [PDF]
, 2006 A new cyclohexyl based fluorescent anion receptor, is able to recognize maleate versus fumarate both as their TMA salts.Costero Nieto, Ana Maria, Ana.Costero@uv.es ; Colera Llavata, Manuel, Manuel.Colera@uv.es ; Gaviña Costero, Pablo, Pablo.Gavina@uv.es ;
Colera Llavata, Manuel +3 more
core +2 more sources
Photoluminescence of Mechanochemically Manufactured Rare‐Earth Doped CsPbCl3 Microcrystals
Advanced Photonics Research, EarlyView.The mechanochemical approach presented in this work allows for exceptional control over dopant incorporation, producing high‐quality powders suited to melt‐growth of single crystals. Through complementary structural characterization techniques (X‐ray diffraction, energy‐dispersive X‐ray spectroscopy, and X‐ray fluorescence), the nominal doping ...
Morris E. Olumba +8 more
wiley +1 more source
Advanced Synthesis &Catalysis, EarlyView.A dual photocatalytic system of o‐PQ and Sn(OTf)2 enables visible light‐induced Mannich‐type addition of ethers to nitrones via Csp³–H activation. This oxidant‐free method offers broad scope and good yields. Mechanistic studies suggest that a photoexcited o‐PQ–Sn(II) complex mediates hydrogen atom transfer to form α‐oxy radicals for nitrone addition. A
Pradip Ramdas Thorve +2 more
wiley +1 more source
CXIX.—The formation and stability of spiro-compounds. Part I. spiro-Compounds from cyclohexane [PDF]
, 1915 Richard Moore Beesley +2 more
openalex +1 more source