Results 251 to 260 of about 111,262 (332)

Unveiling Solvent‐Dependent Divergent Hydrogen Production Pathways during the Dehydrogenation of Formic Acid Using N,N′‐Iminopyridine Ruthenium(II) Complexes

European Journal of Inorganic Chemistry, EarlyView.
A readily available, efficient RuII catalyst mediates hydrogen production via formic acid dehydrogenation, via distinct, solvent‐dependent hydrogen production pathways. In water, catalyst robustness is observed, generating turnover numbers (TONs) of 13 791 under stepwise addition, while displaying sustained activity under continuous addition conditions
Thabiso Mphuti, Rotondwa Mphephu, Moegamat Joseph, Andrew J. Swarts   +3 more
wiley   +1 more source

Substrate Preorganization Within Photoactive Pt₁₂L₂₄ Nanospheres for Accelerated Decarboxylation Catalysis at Low Concentrations. [PDF]

Angew Chem Int Ed Engl
Ham R, Baumgartner B, Reek JNH.
europepmc   +1 more source

The Dihydroindeno[2,1‐c]fluorene Core: From Syntheses to Properties and Potential Applications

European Journal of Organic Chemistry, EarlyView.
In this review, the latest research progress in synthesis and application of variously decorated aromatic compounds possessing the indeno[2.1‐c]fluorene scaffold is summarized. In addition to covering synthetic endeavors, their transformation to other structurally related aromatic compounds and their physical properties and possible applications are ...
Timothée Cadart, Martin Kotora
wiley   +1 more source

Intramolecular PCET of α-Keto Acids: Synthesis of Trifluoromethyl Ketones via Ketyl Radicals. [PDF]

Chemistry
Nabi RN, Jarquin KA, Karmakar A, Brunner KE, Kim DK.   +4 more
europepmc   +1 more source

Hydrogen peroxide ‐ responsive aminoferrocene prodrugs

European Journal of Organic Chemistry, Accepted Article.
Aminoferrocene (AF)‐based prodrugs are activated in cancer cells through reactions with H₂O₂ and other reactive oxygen species (ROS), generating electron‐rich AF’s. These, in turn, induce the production of highly toxic O2·‐ and HO·, leading to cancer cell death.
Marlies Körber, Jennifer Rühle, Fabian Halter, Andriy Mokhir   +3 more
wiley   +1 more source

Incomplete Decarboxylation of Acidic Cannabinoids in GC-MS Leads to Underestimation of the Total Cannabinoid Content in Cannabis Oils Without Derivatization. [PDF]

Pharmaceutics
Franzin M, Di Lenardo R, Ruoso R, Addobbati R.   +3 more
europepmc   +1 more source

Identifying the True Catalyst: A Mn(II) Salt versus Mn(II) Complexes in Epoxidation with m‐Chloroperbenzoic Acid

European Journal of Organic Chemistry, EarlyView.
During the investigation of the reactivity of three Mn complexes, Mn(ClO4)2 shows higher reactivity toward styrene epoxidation, indicating that ligand coordination inhibits the reactivity of the manganese center. Raman spectroscopy provides mechanistic insight: monitoring alkene epoxidation and consumption of the oxidant over time, the true nature of ...
Milica Savić, Aleksandra Mitrović, Božidar Čobeljić, Andrej Pevec, Matija Zlatar, Maja Gruden, Wesley R. Browne, Marika Di Berto Mancini   +7 more
wiley   +1 more source

Characterization of a consensus-designed <i>trans</i>-cinnamic acid decarboxylase for styrene biosynthesis. [PDF]

mBio
García-Franco A, de la Torre J, Godoy P, Duque E, López C, Gavira JA, Ramos JL.   +6 more
europepmc   +1 more source

Decarboxylative Michael Additions of Substituted Malonic Acid Half‐Oxyesters to Methylidene Malonates

European Journal of Organic Chemistry, EarlyView.
Substituted malonic acid half oxyesters reacted with alkylidene malonates in a fast, efficient decarboxylative Michael addition, delivering adducts in high yields. The reaction occurred in bulk solvent, open to air, needing only a weak amine base as an organocatalyst to drive a mechanism involving addition prior to decarboxylation.
Marine Pinaud, Tania Xavier, Léa Lin, Erwan Le Gall, Marc Presset   +4 more
wiley   +1 more source

Unlocking Chromium Decarboxylative Ligand-to-Metal Charge Transfer: Efficient and Redox-Neutral Allylation of Aldehydes Using Carboxylic Acids. [PDF]

J Am Chem Soc
Wu S, Jiao Z, Sung AT, Faulhaber AB, Schley ND, Schuppe AW.   +5 more
europepmc   +1 more source