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Enantioselective Desymmetrization of Tropinone Derivatives by Hydroboration

Synlett, 2003
N-Protected tropenone derivs. I (R = CO2Me, CBZ, Ts) prepd. from the resp. pyrroles and tetrabromoacetone, were used as starting materials for desymmetrization by hydroboration of the C-C double bond. Hydroboration of I with (-)-(Ipc)2BH followed by oxidn., however, gave the desired 6-hydroxylated product only in low yield due to byproduct formation ...
Cramer, Nicolai   +3 more
openaire   +1 more source

Desymmetrization

2011
K. Matsumoto   +2 more
openaire   +1 more source

Desymmetrizations

2012
K. Hof, K. M. Lippert, P. R. Schreiner
openaire   +1 more source

Chiral Phosphoric Acid–Palladium(II) Complex Catalyzed Asymmetric Desymmetrization of Biaryl Compounds by C(sp3)–H Activation

Journal of the American Chemical Society, 2023
Masahiro Yamanaka   +2 more
exaly  

Enantioselective Desymmetrization

2008
S. W. Roberts, J. D. Rainier
openaire   +1 more source

Enantioselective Desymmetrization of Cyclobutanones: A Speedway to Molecular Complexity

Angewandte Chemie - International Edition, 2020
Johannes M Wahl, Jan Sietmann
exaly  

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