K<sup>+</sup>/Cu<sup>2+</sup> Co-chelated diastereoselective Friedel-Crafts reaction with chiral <i>N</i>-sulfinyl ketimines for the facile synthesis of chiral bisindoles and their cytotoxicity. [PDF]
Yan S +11 more
europepmc +1 more source
A mild, metal‐free photochemical decarboxylative allylic alkylation protocol using inexpensive thioxanthone under blue LEDs couples diverse carboxylic and N‐protected amino acids with Morita–Baylis–Hillman derivatives, offering broad substrate scope and a mechanism supported by radical‐trapping experiments.
Areti N. Karamitrou +3 more
wiley +1 more source
N‐Aryl Acridone Derivatives as Effective Catalysts for Energy Transfer Reactions
Acridones derivatives have high triplet energy, are simple accessible, and could be used in challenging [2+2] ENT reactions. ABSTRACT Organic photocatalysts capable of promoting high‐energy triplet energy transfer (EnT) remain limited, particularly for demanding [2+2] photocycloaddition reactions.
Francesco Calogero +8 more
wiley +1 more source
Synthesis and systematic evaluation of four stereoisomers of BMS compound A enabled by a diastereoselective cyclopropanation on a chiral ketal intermediate. [PDF]
Wang F +11 more
europepmc +1 more source
A stereodivergent route from D‐mannitol enables access to enantiopure C5‐α‐substituted linezolid analogues with full configurational control. Biological evaluation reveals that α‐substitution abolishes antibacterial activity irrespective of stereochemistry, establishing a strict steric limitation at C5 and highlighting the dominant role of substituent ...
José A. Gálvez +3 more
wiley +1 more source
Diastereoselective and green synthesis of novel Hexahydro Imidazo [1,2-a] pyrimidine, from Azlactones, Brimonidine and Clonidine. [PDF]
Rahmati K +3 more
europepmc +1 more source
Stereoselective Construction of Benzo‐Fused Tetrahydropyrrole Thiazines From Saccharin
Saccharin was used as a template to construct a series of 10a‐substituted, benzo‐fused, pyrrolo thiazinone dioxides. Thereafter, diastereo‐divergent 10‐keto reduction gave either diastereomeric alcohol in a process that did not rely on the substituent at 10a's identity.
Seanán Doyle +8 more
wiley +1 more source
Recent Advances in Intramolecular C─N Bond Formation for Pyrrolidine Synthesis. [PDF]
Kroņkalne R, Turks M.
europepmc +1 more source
Copper-Catalyzed Diastereoselective Defluoroborylation of Pentafluoroethyl Alkenes Using (pin)B-B(dan). [PDF]
Tang Y, Tsui GC.
europepmc +1 more source

