Synthesis of Levoglucosenone‐Based Amphiphilic Molecules via Microwave‐Assisted Michael Additions
Comparison between the conventional and the sustainable synthetic microwave‐based approach for Michael addition reactions on LGO developed in this work. Aligning with the objectives of the EU chemicals strategy for sustainability, an ultrarapid, safe and sustainable method for producing a library of levoglucosenone (LGO)‐based amphiphilic molecules was
Maria Jose Calandri +8 more
wiley +1 more source
NaHMDS/B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-promoted diastereoselective Friedel-Crafts alkylation of indoles/pyrroles with <i>N-tert</i>-butanesulfinylimines: towards the asymmetric synthesis of bisindole alkaloid Calcicamide B. [PDF]
Zhang G +11 more
europepmc +1 more source
This review surveys the literature on light‐driven dearomative [2+2] cycloadditions of indoles, highlighting their power to access complex cyclobuta[b]indole frameworks. Advances in photocatalysis, sensitizer design, and reaction engineering enable selective and sustainable assembly of strained three‐dimensional architectures, expanding opportunities ...
Maria Chiara Cabua +4 more
wiley +1 more source
Diastereoselective synthesis of novel (S)-lactic pyrazoline derivatives and investigation of antibacterial capabilities. [PDF]
Gholami M +4 more
europepmc +1 more source
1,2‐Bisborylalkanes are valuable intermediates for chemical synthesis as they could serve as a platform to generate value‐added products with two distinct functional groups at vicinal positions. A novel strategy to synthesize 1,2‐bisborylalkanes via Fe ligand‐to‐metal charge transfer (LMCT) photocatalysis is developed.
Zheye Zhang +5 more
wiley +2 more sources
Copper-Catalyzed Diastereoselective Defluoroborylation of Pentafluoroethyl Alkenes Using (pin)B-B(dan). [PDF]
Tang Y, Tsui GC.
europepmc +1 more source
Intelligent Molecular Recognition in Hydrogen‐Bond‐Mediated Supramolecular Polyhedra
This perspective highlights the construction of sophisticated hydrogen‐bonded supramolecular polyhedra from macrocycles by emulating the hierarchical assembly of ferritin and viral capsids, and summarizes their selective recognition of individual guest molecules as well as the synergistic encapsulation of multiple species, demonstrating their potential
Ran‐Qi Chen +3 more
wiley +1 more source
Diastereoselective synthesis of cyclopropyl sulfoxides <i>via</i> hydrosulfenation. [PDF]
Yuwen L +6 more
europepmc +1 more source
Advances in the Different Synthetic Routes of Fluorinated Hydrazines
This review highlights the various routes to the preparation of fluorinated hydrazines, thereby promoting the exploration of innovative methods for the synthesis of new N‐fluorinated hydrazines. Their synthesis mainly involves synthetic routes such as organometallic, organocatalytic, and photocatalytic.
Dimitra Kyrko, Benoît Crousse
wiley +1 more source
Stereocontrolled Synthesis of Polysubstituted Housanes via <i>gem</i>-Bismetalated Cyclopropanes. [PDF]
Orbach N, Suresh R, Marek I.
europepmc +1 more source

