Diastereoselective Synthesis of Axially Chiral Skipped Ene-Allenes Containing a Quaternary Stereocenter by Cyclopropene-Allene Metathesis. [PDF]
Chen B, Zhou Y, Ho CY, Huang JQ.
europepmc +1 more source
Truncation of Samroiyotmycin: Tailored seco‐Acids as Novel Antimalaria Compounds
Six truncated samroiyotmycin‐derived antimalarials were synthesized by replacing the tosyloxazole unit with electron‐deficient aryl groups. The most active seco‐acid with EWG = 2 × CF3 outperformed the natural product SamA. Its enhanced activity supports a donor–acceptor interaction involving the electron‐poor aryl unit, consistent with inhibition of ...
Anton Czuczkowski +10 more
wiley +1 more source
Diastereoselective Synthesis of α‑Fluoro-γ-lactams via Difluorocarbene-Triggered Cyclization and Rearrangement. [PDF]
Jabbarpoor M +5 more
europepmc +1 more source
Sigmatropic rearrangements of ynamides in stereoselective synthesis of complex molecular architectures: a comprehensive review. [PDF]
Mishra A, Pati SS, Das JP.
europepmc +1 more source
Sulfur Ylide-Mediated [2 + 1] Annulation for the Synthesis of Spiro[cyclopropane-indolizine] Derivatives. [PDF]
Li ZY +6 more
europepmc +1 more source
Synthesis of Tronocarpine Framework via a Michael/Lactamization/Michael Cascade Process: Synthesis of Dihydrotronocarpine. [PDF]
Castañón-Garcíaa M +2 more
europepmc +1 more source
A new class of “super‐strained” spiro heterocycles—spirocyclic 1‐azabicyclo[1.1.0]butanes—was synthesized via insertion of cyclobutane‐, oxetane‐, and azetidine‐containing sulfonium reagents into substituted azirines. The stability of this new class of compounds was studied.
Philipp Natho +9 more
wiley +2 more sources
Interrupted Reactions in the Synthesis of Subrubine Alkaloids. [PDF]
Golijanin J, Fagu LR, Yudin AK.
europepmc +1 more source
Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source

