Asymmetric Deoxy-Fluoroalkylation of Amides Enabled by Transimination. [PDF]
Wilt JA +7 more
europepmc +1 more source
Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley +1 more source
Rongalite addition to dienones: diastereoselectivity in cyclic sulfone synthesis; stereochemical rationalization and prospects as a general conjugate nucleophile. [PDF]
Goga M +9 more
europepmc +1 more source
Isotelluroureas for Asymmetric C1 Ammonium Enolate Reactions
Chiral isotelluroureas are powerful catalysts for a variety of C─C bond forming C1 ammonium enolate transformations. Isotelluroureas (ITeUs) have recently been introduced as a novel class of highly nucleophilic Lewis base catalysts. Herein, we systematically screened them for their potential to facilitate C1 ammonium enolate transformations and ...
Fereshteh Khorasani +3 more
wiley +1 more source
Pd/C-Catalyzed Hydrogenation of CF<sub>3</sub>-, CF<sub>2</sub>H-, and CF<sub>2</sub>CO<sub>2</sub>Et-containing Pyridines: A Robust Method for Highly Functionalized containing Piperidines. [PDF]
Charvillat T +7 more
europepmc +1 more source
Beyond para- and meta-Substitution: Synthesis and Biological Validation of Chalcogen-Rich Thiabicyclo[3.1.1]heptanes as Bioisosteres of Aryl Thioether Derivatives. [PDF]
Wang KJ +9 more
europepmc +1 more source
Catalytically Promiscuous PLP-Dependent Aminotransferases Are Biocatalysts for C-C Bond Formation. [PDF]
Kim AT +6 more
europepmc +1 more source
Photoinduced cobalt-catalyzed enantioconvergent synthesis of 1,3-diamines via aziridine ring-opening addition. [PDF]
Xia T +6 more
europepmc +1 more source
Remote Stereocontrol in Aryl/Alkyl C-H Insertion Reactions of Rhodium Carbenes: Assembly of Pseudorigidols A and B. [PDF]
Ung L +4 more
europepmc +1 more source
Diastereoselective spiroannulation of phenolic derivatives: Effect of steric hindrance on the diastereoselectivity. [PDF]
openaire +1 more source

