Results 11 to 20 of about 66,029 (249)

Exploring the Limits of Reactivity of N-Methyl-1,2,4-triazoline-3,5-dione (MeTAD) with Disubstituted Bicycloalkadienes in the Homo-Diels–Alder Reaction

open access: yesOrganics, 2022
The [2+2+2] cycloaddition (homo-Diels–Alder reaction) of N-substituted 1,2,4-triazoline-3,5-diones (TADs) with bicycloalkadienes produces strained heterocyclic compounds.
Gary W. Breton, Kenneth L. Martin
doaj   +1 more source

Self-assembly using a retro Diels-Alder reaction

open access: yesNature Communications, 2021
Despite their great utility in synthetic and materials chemistry, Diels-Alder and retro Diels-Alder reactions have been vastly unexplored in promoting self-assembly processes.
Jaeyoung Park   +4 more
doaj   +1 more source

Enzymatic intermolecular Diels-Alder reactions in synthesis: From nature to design

open access: yesTetrahedron Chem, 2022
The Diels-Alder (D-A) reaction is one of the most critical chemical transformations to construct C–C bonds with predictable regio- and stereo-selectivities. It has been widely used as a retrosynthetic disconnection in synthetic chemistry.
Lei Gao, Jun Yang, Xiaoguang Lei
doaj   +1 more source

Reversible Diels–Alder Reactions with a Fluorescent Dye on the Surface of Magnetite Nanoparticles

open access: yesMolecules, 2021
Diels–Alder reactions on the surface of nanoparticles allow a thermoreversible functionalization of the nanosized building blocks. We report the synthesis of well-defined magnetite nanoparticles by thermal decomposition reaction and their ...
Siyang He, Guido Kickelbick
doaj   +1 more source

One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones

open access: yesGreen Synthesis and Catalysis, 2020
Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields.
Xixi Song   +5 more
doaj   +1 more source

Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions

open access: yesMolecules, 2021
The Diels–Alder cycloaddition between bisdienes and bisdienophile incorporating the 7-oxa-bicyclo[2.2.1]heptane unit are well known to show high diastereoselectivity that can be exploited for the synthesis of molecular belts. The related bisdiene 5,6,7,8-
John B. Bauer   +4 more
doaj   +1 more source

Bio-Based Aromatic Polyesters Reversibly Crosslinked via the Diels–Alder Reaction

open access: yesApplied Sciences, 2022
Diphenolic acid is functionalized with furfuryl amine and subsequently incorporated in a (partly) bio-based polyester through interfacial polycondensation with terepthalic chloride.
Martijn Beljaars   +3 more
doaj   +1 more source

Exploiting double exchange Diels-Alder cycloadditions for immobilization of peptide nucleic acids on gold nanoparticles [PDF]

open access: yes, 2020
The generation of PNA-decorated gold nanoparticles (AuNPs) has revealed to be more difficult as compared to the generation of DNA-functionalized ones. The less polar nature of this artificial nucleic acid system and the associated tendency of the neutral
Cadoni, Enrico   +4 more
core   +2 more sources

Characterization and kinetic study of Diels-Alder reaction: Detailed study on N-phenylmaleimide and furan based benzoxazine with potential self-healing application

open access: yeseXPRESS Polymer Letters, 2016
The Diels-Alder reaction between N-phenylmaleimide and benzoxazine bearing furan group was investigated for the purpose of successful appliance of self-healing in benzoxazine polymer networks.
Z. Stirn, A. Rucigaj, M. Krajnc
doaj   +1 more source

The Catalytic Mechanism of a Natural Diels-Alderase Revealed in Molecular Detail [PDF]

open access: yes, 2016
The Diels-Alder reaction, a [4 + 2] cycloaddition of a conjugated diene to a dienophile, is one of the most powerful reactions in synthetic chemistry. Biocatalysts capable of unlocking new and efficient Diels-Alder reactions would have major impact. Here
Byrne, Matthew J.   +7 more
core   +2 more sources

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