Results 11 to 20 of about 66,029 (249)
The [2+2+2] cycloaddition (homo-Diels–Alder reaction) of N-substituted 1,2,4-triazoline-3,5-diones (TADs) with bicycloalkadienes produces strained heterocyclic compounds.
Gary W. Breton, Kenneth L. Martin
doaj +1 more source
Self-assembly using a retro Diels-Alder reaction
Despite their great utility in synthetic and materials chemistry, Diels-Alder and retro Diels-Alder reactions have been vastly unexplored in promoting self-assembly processes.
Jaeyoung Park +4 more
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Enzymatic intermolecular Diels-Alder reactions in synthesis: From nature to design
The Diels-Alder (D-A) reaction is one of the most critical chemical transformations to construct C–C bonds with predictable regio- and stereo-selectivities. It has been widely used as a retrosynthetic disconnection in synthetic chemistry.
Lei Gao, Jun Yang, Xiaoguang Lei
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Reversible Diels–Alder Reactions with a Fluorescent Dye on the Surface of Magnetite Nanoparticles
Diels–Alder reactions on the surface of nanoparticles allow a thermoreversible functionalization of the nanosized building blocks. We report the synthesis of well-defined magnetite nanoparticles by thermal decomposition reaction and their ...
Siyang He, Guido Kickelbick
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Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields.
Xixi Song +5 more
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Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions
The Diels–Alder cycloaddition between bisdienes and bisdienophile incorporating the 7-oxa-bicyclo[2.2.1]heptane unit are well known to show high diastereoselectivity that can be exploited for the synthesis of molecular belts. The related bisdiene 5,6,7,8-
John B. Bauer +4 more
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Bio-Based Aromatic Polyesters Reversibly Crosslinked via the Diels–Alder Reaction
Diphenolic acid is functionalized with furfuryl amine and subsequently incorporated in a (partly) bio-based polyester through interfacial polycondensation with terepthalic chloride.
Martijn Beljaars +3 more
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Exploiting double exchange Diels-Alder cycloadditions for immobilization of peptide nucleic acids on gold nanoparticles [PDF]
The generation of PNA-decorated gold nanoparticles (AuNPs) has revealed to be more difficult as compared to the generation of DNA-functionalized ones. The less polar nature of this artificial nucleic acid system and the associated tendency of the neutral
Cadoni, Enrico +4 more
core +2 more sources
The Diels-Alder reaction between N-phenylmaleimide and benzoxazine bearing furan group was investigated for the purpose of successful appliance of self-healing in benzoxazine polymer networks.
Z. Stirn, A. Rucigaj, M. Krajnc
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The Catalytic Mechanism of a Natural Diels-Alderase Revealed in Molecular Detail [PDF]
The Diels-Alder reaction, a [4 + 2] cycloaddition of a conjugated diene to a dienophile, is one of the most powerful reactions in synthetic chemistry. Biocatalysts capable of unlocking new and efficient Diels-Alder reactions would have major impact. Here
Byrne, Matthew J. +7 more
core +2 more sources

