Results 21 to 30 of about 66,029 (249)

Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles [PDF]

open access: yes, 2002
4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans.
Ducept, P.C., Marsden, S.P.
core   +1 more source

Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction

open access: yesMolecules, 2007
The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel Ti(IV) performance catalyst.
Kyle E. Litz
doaj   +1 more source

Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries [PDF]

open access: yes, 2016
Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state.
Cooke, Graeme   +5 more
core   +1 more source

Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]

open access: yes, 2009
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Desrat, S, van de Weghe, P
core   +3 more sources

An Asymmetric Synthetic Approach to the A-ring of the Taxol Family of Anti-Cancer Compounds

open access: yesMolecules, 1998
A synthetic route developed for the preparation of the A-ring of Taxol family of molecules is reported. By means of an intramolecular Diels-Alder reaction an asymmetric approach to this ring has been accomplished.
M. L. Marin, D. Craig
doaj   +1 more source

Quinones as dienophiles in the Diels-Alder reaction: history and applications in total synthesis [PDF]

open access: yes, 2014
In the canon of reactions available to the organic chemist engaged in total synthesis, the Diels–Alder reaction is among the most powerful and well understood. Its ability to rapidly generate molecular complexity through the simultaneous formation of two
Albrecht   +159 more
core   +2 more sources

The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings

open access: yesPolímeros, 2005
The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character.
Alessandro Gandini
doaj   +1 more source

Preparation of optically active cis-4-methylcyclohex-4-ene-1,2-dicarboximides by a combination of Diels–Alder reaction and complexation with optically active hosts and enantioselective Diels–Alder reaction in inclusion crystals in a water suspension medium [PDF]

open access: yes, 2003
Optically active Diels–Alder adducts were prepared using a one-pot preparative method and enantioselective Diels–Alder reaction with optically active hosts in a water suspension ...
Daikawa Naoki   +7 more
core   +2 more sources

The influence of reaction conditions on the Diels-Alder cycloadditions of 2-thio-3-chloroacrylamides; investigation of thermal, catalytic and microwave conditions [PDF]

open access: yes, 2010
The Diels-Alder cycloadditions of cyclopentadiene and 2,3-dimethyl-1,3-butadiene to a range of 2-thio-3-chloroacrylamides under thermal, catalytic and microwave conditions is described.
Chopra, Jay   +4 more
core   +1 more source

Data on production and characterization of melamine-furan-formaldehyde particles and reversible reactions thereof

open access: yesData in Brief, 2019
The data present in this article affords insides in the characterization of a newly described bi-functional furan-melamine monomer, which is used for the production of monodisperse, furan-functionalized melamine-formaldehyde particles, as described in ...
Katharina Urdl   +6 more
doaj   +1 more source

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