Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles [PDF]
4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans.
Ducept, P.C., Marsden, S.P.
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Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction
The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel Ti(IV) performance catalyst.
Kyle E. Litz
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Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries [PDF]
Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state.
Cooke, Graeme +5 more
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Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Desrat, S, van de Weghe, P
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An Asymmetric Synthetic Approach to the A-ring of the Taxol Family of Anti-Cancer Compounds
A synthetic route developed for the preparation of the A-ring of Taxol family of molecules is reported. By means of an intramolecular Diels-Alder reaction an asymmetric approach to this ring has been accomplished.
M. L. Marin, D. Craig
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Quinones as dienophiles in the Diels-Alder reaction: history and applications in total synthesis [PDF]
In the canon of reactions available to the organic chemist engaged in total synthesis, the Diels–Alder reaction is among the most powerful and well understood. Its ability to rapidly generate molecular complexity through the simultaneous formation of two
Albrecht +159 more
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The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character.
Alessandro Gandini
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Preparation of optically active cis-4-methylcyclohex-4-ene-1,2-dicarboximides by a combination of Diels–Alder reaction and complexation with optically active hosts and enantioselective Diels–Alder reaction in inclusion crystals in a water suspension medium [PDF]
Optically active Diels–Alder adducts were prepared using a one-pot preparative method and enantioselective Diels–Alder reaction with optically active hosts in a water suspension ...
Daikawa Naoki +7 more
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The influence of reaction conditions on the Diels-Alder cycloadditions of 2-thio-3-chloroacrylamides; investigation of thermal, catalytic and microwave conditions [PDF]
The Diels-Alder cycloadditions of cyclopentadiene and 2,3-dimethyl-1,3-butadiene to a range of 2-thio-3-chloroacrylamides under thermal, catalytic and microwave conditions is described.
Chopra, Jay +4 more
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The data present in this article affords insides in the characterization of a newly described bi-functional furan-melamine monomer, which is used for the production of monodisperse, furan-functionalized melamine-formaldehyde particles, as described in ...
Katharina Urdl +6 more
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