Standardized Approach for Diversification of Complex Small Molecules via Aryl Thianthrenium Salts. [PDF]
Ahmadli D +7 more
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Synthesis of CHF2-Containing Heterocycles through Oxy-difluoromethylation Using Low-Cost 3D Printed PhotoFlow Reactors. [PDF]
Zhang J +6 more
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Photo/electro-mediated radical cascade functionalization/cyclization reactions involving <i>N</i>-acryloyl 2-aryl indoles/benzimidazoles. [PDF]
Doraghi F +6 more
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Why •CF2H is nucleophilic but •CF3 is electrophilic in reactions with heterocycles. [PDF]
Duan M +4 more
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Photocatalytic remote C(sp<sup>3</sup>)-H alkylation of long-chain alkenes: A tandem multicomponent approach <i>via</i> radical translocation. [PDF]
Ghosh KG +4 more
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Recent Advances in the High-Value Conversion of Alkenes Induced by Electrochemistry. [PDF]
Liang X, Wang H, Xie W, Liu Z, Qin D.
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Dawn of photoredox catalysis. [PDF]
Akita M.
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Difluoromethylation Reactions of Organic Compounds
Chemistry - A European Journal, 2017AbstractThe relevance of the ‐CF2H moiety has attracted considerable attention from organic synthetic and medicinal chemistry communities, because this group can act as a more lipophilic isostere of the carbinol, thiol, hydroxamic acid, or amide groups.
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A photoredox-catalyzed direct difluoromethylation of alkynoates has been developed.
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Difluoroacetic Acid as a New Reagent for Direct C−H Difluoromethylation of Heteroaromatic Compounds
A technically simple procedure for direct C-H difluoromethylation of heteroaromatic compounds using off-the-shelf difluoroacetic acid as the difluoromethylating reagent has been developed.
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