Results 51 to 60 of about 1,907 (195)

Catalytic Antioxidant Activity of Acyclic and Macrocyclic Selenides: Insights Into Structure–Activity Relationships and Mechanisms From Kinetic and Computational Studies

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Structure–activity relationships of antioxidant activities of selenides were established by experimental and computational methods. Several structures displayed strong catalytic activity in an NMR‐based assay. Diverse selenides were shown to act as potent catalytic antioxidants.
Adrian I. Doig, Wen Zhou, Thomas G. Back
wiley   +1 more source

Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer

open access: yesAngewandte Chemie, Volume 138, Issue 4, 22 January 2026.
The first series of fully characterized homoleptic alkynyl bismuth compounds Bi(C≡CR)3 is presented. Facile homolytic Bi–C bond cleavage grants access to alkynyl radicals, which have been employed in selective C–X bond formation (X = C, B, Se, Te). This complements existing strategies for alkynyl radical generation as it proceeds under mild and purely ...
Gargi Kundu   +5 more
wiley   +2 more sources

Influence of Diphenyl Diselenide on Thiol Redox Homeostasis and Electrogenic Membrane Transport in Rotenone-Induced Parkinson’s Disease

open access: yesbioRxiv, 2022
The central role of oxidative stress in the etiology of Parkinsons disease defines a key therapeutic role for antioxidant compounds in the management of the disease.
T. I. Ologunagba   +4 more
semanticscholar   +1 more source

Unraveling the Physicochemical Landscape of Organoselenium Compounds in Nanocarrier Systems

open access: yesThe Chemical Record, EarlyView.
Main nanocarriers employed to enhance the bioavailability and transport of organoselenium compounds. The image illustrates the key interaction forces that stabilize these organoselenium species in solution, enabling their application in drug delivery systems, catalysis, photoelectronic devices, and sensing technologies. In recent years, publications on
Romelly Eugenia Rojas Ramírez   +3 more
wiley   +1 more source

A Para‐Selective Kolbe–Schmitt Reaction

open access: yesAngewandte Chemie, Volume 138, Issue 4, 22 January 2026.
Discovered over 150 years ago, the Kolbe–Schmitt carboxylation has established itself as one of the most well‐known chemical reactions. However, the process often requires extreme pressures and high temperatures. Here, we present a unique para‐selective Kolbe–Schmitt‐type carboxylation that proceeds at relatively low temperatures and uses near ...
Xia Liu   +2 more
wiley   +2 more sources

Diphenyl Diselenide and Clotrimazole Co-loaded into Eudragit® RS 100 Nanocapsules Formulation Has Superior Antioxidant Potential and Promising Anti-candida Activity [PDF]

open access: yesBrazilian Archives of Biology and Technology, 2020
In the current study, nanocapsules (NC) formulations containing a co-load of clotrimazole (C), a highly prescribed antifungal drug, and diphenyl diselenide [(PhSe)2], an organoselenium compound with a promising scope of pharmacological actions, were ...
Andrei Vinícius Englert   +4 more
doaj   +1 more source

Reversible Dihydrogen Splitting and Diradical Reactivity of 1,4‐Digermabenzene‐1,4‐diide

open access: yesChemistryEurope, Volume 4, Issue 5, May 2026.
The diradical reactivity of the 1,4‐digermabenzene‐1,4‐diide, [(ADC)Ge]2, has been demonstrated with a range of substrates. Notably, it undergoes reversible dihydrogen splitting and radical coupling with TEMPO (2,2,6,6‐tetramethylpiperidinyloxyl = RO), forming [(ADC)GeH]2 and [(ADC)Ge(OR)]2, respectively.
Falk Ebeler   +5 more
wiley   +1 more source

Electrochemical Regioselective Chalcogenocyclizations of 2‐Alkynylbenzamides in Flow

open access: yesChemElectroChem, Volume 13, Issue 8, 15 April 2026.
A sustainable electrochemical method enables regioselective 6‐endo‐dig chalcogeno‐cyclizations of ortho‐alkynylbenzamides in continuous flow. Using diphenyl diselenide as an electroactive coupling partner, the process avoids metals and stoichiometric oxidants, offering scalable access to selenium‐containing heterocycles.
Hanaa Gieman   +2 more
wiley   +1 more source

Electro‐Mediated Redox Functionalization of Conjugated 1,3‐Dienes

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 6, 17 March 2026.
This review aims at providing a comprehensive view of the emerging field of electro‐mediated functionalization of conjugated 1,3‐dienes, highlighting key developments, mechanistic insights, and remaining challenges. It highlights the efficient use of electron as the sole reagent to access highly substituted allylic compounds from simple and readily ...
Ophélie Montiège   +3 more
wiley   +1 more source

Nitrogen‐Doped Graphene Aerogels for Supercapacitors: Advances in Synthesis and Electrochemical Performance

open access: yesBattery Energy, Volume 5, Issue 2, March 2026.
This review explores nitrogen‐doped graphene aerogel materials used in supercapacitors, analyzing synthesis techniques, performance measures, and recent advancements. It highlights material challenges and limitations while suggesting directions for future research.
Khaled Abdou Ahmed Abdou Elsehsah   +6 more
wiley   +1 more source

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