Results 111 to 120 of about 25,921 (206)

Stereoselective Intramolecular Azide 1,3-Dipolar Cycloaddition

open access: yesHETEROCYCLES, 2003
Ethyl (E)-7-azido-6-[bis(tert-butoxycarbonyl)amino]-2-heptenoate undergoes a stereoselective intramolecular azide 1,3-dipolar cycloaddition leading to a stable triazoline. The configuration and the conformation of the triazoline obtained were determined by spectroscopic data and confirmed by molecular mechanics calculations.
Markidis, T., Mikros, E., Kokotos, G.
openaire   +2 more sources

1,3‐Dipolar Cycloaddition of Dipolar Reagents to Bis(styryl) Sulfones.

open access: yesChemInform, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
V. Padmavathi   +4 more
openaire   +1 more source

Synthesis of some isoxazoline, isoxazole and pyrazole carboxylic acids as the precursors of new 1,2-diacyl-1-alkylhydrazines [PDF]

open access: yes, 2013
A number of isoxazoline, isoxazole and pyrazole carboxylic acids or their esters has been synthesized via the 1,3-dipolar cycloaddition of corresponding nitrile oxides or diazomethane to unsaturated dipolarophiles.
Antonevich, I. P., Katok, Ya. M.
core  

Synthesis of new triazole-based trifluoromethyl scaffolds

open access: yesBeilstein Journal of Organic Chemistry, 2008
Trifluoromethyl propargylamines react with various azide derivatives to afford 1,4-disubstituted 1,2,3-triazoles through a Huisgen 1,3-dipolar cycloaddition. The reaction is catalyzed by a Cu(I) species in acetonitrile, and the corresponding products are
Michela Martinelli   +3 more
doaj   +1 more source

Theory of Distinct Crystal Structures of Polymerized Fullerides AC60, A=K, Rb, Cs: the Specific Role of Alkalis

open access: yes, 2000
The polymer phases of AC60 form distinct crystal structures characterized by the mutual orientations of the (C60-)n chains. We show that the direct electric quadrupole interaction between chains always favors the orthorhombic structure Pmnn with ...
A. Hüller   +27 more
core   +1 more source

Cyaphide-Azide 1,3-Dipolar Cycloaddition Reactions: Scope and Applicability. [PDF]

open access: yesChemistry, 2023
Yang ES   +4 more
europepmc   +1 more source

Asymmetric formal [1 + 2 + 2]-cycloaddition of diazoamides with enamines and carbonyl compounds

open access: yesNature Communications
Cycloaddition reaction offers an ideal and powerful method for the construction of cyclic structures with molecular complexity and diversity.
Shanliang Dong   +5 more
doaj   +1 more source

Highly Regioselective 1,3-Dipolar Cycloaddition of Nitrilimines and Thioaurones Towards Spiro-2-Pyrazolines: Synthesis, Characterization, and Mechanistic Study

open access: yesReactions
In this paper, we report a highly regioselective 1,3-dipolar cycloaddition (1,3-DC) reaction of nitrilimines with thioaurone derivatives that afforded the hitherto unreported spiropyrazolines. Spectroscopic and spectrometric data were utilized to confirm
Mohamed Bakhouch   +10 more
doaj   +1 more source

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