Stereoselective Intramolecular Azide 1,3-Dipolar Cycloaddition
Ethyl (E)-7-azido-6-[bis(tert-butoxycarbonyl)amino]-2-heptenoate undergoes a stereoselective intramolecular azide 1,3-dipolar cycloaddition leading to a stable triazoline. The configuration and the conformation of the triazoline obtained were determined by spectroscopic data and confirmed by molecular mechanics calculations.
Markidis, T., Mikros, E., Kokotos, G.
openaire +2 more sources
1,3‐Dipolar Cycloaddition of Dipolar Reagents to Bis(styryl) Sulfones.
AbstractFor Abstract see ChemInform Abstract in Full Text.
V. Padmavathi +4 more
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Synthesis of some isoxazoline, isoxazole and pyrazole carboxylic acids as the precursors of new 1,2-diacyl-1-alkylhydrazines [PDF]
A number of isoxazoline, isoxazole and pyrazole carboxylic acids or their esters has been synthesized via the 1,3-dipolar cycloaddition of corresponding nitrile oxides or diazomethane to unsaturated dipolarophiles.
Antonevich, I. P., Katok, Ya. M.
core
Synthesis of new triazole-based trifluoromethyl scaffolds
Trifluoromethyl propargylamines react with various azide derivatives to afford 1,4-disubstituted 1,2,3-triazoles through a Huisgen 1,3-dipolar cycloaddition. The reaction is catalyzed by a Cu(I) species in acetonitrile, and the corresponding products are
Michela Martinelli +3 more
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The polymer phases of AC60 form distinct crystal structures characterized by the mutual orientations of the (C60-)n chains. We show that the direct electric quadrupole interaction between chains always favors the orthorhombic structure Pmnn with ...
A. Hüller +27 more
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Cyaphide-Azide 1,3-Dipolar Cycloaddition Reactions: Scope and Applicability. [PDF]
Yang ES +4 more
europepmc +1 more source
Decarboxylative 1,3-dipolar cycloaddition of amino acids for the synthesis of heterocyclic compounds. [PDF]
Zhang X, Ma X, Zhang W.
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Asymmetric formal [1 + 2 + 2]-cycloaddition of diazoamides with enamines and carbonyl compounds
Cycloaddition reaction offers an ideal and powerful method for the construction of cyclic structures with molecular complexity and diversity.
Shanliang Dong +5 more
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Competing [2 + 3] and [4 + 3] cycloadditions of C,N-diphenylnitrone with 1,3-dienes. Evidence for thermally nonequilibrated intermediates [PDF]
Baran, Janusz, Mayr, Herbert
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In this paper, we report a highly regioselective 1,3-dipolar cycloaddition (1,3-DC) reaction of nitrilimines with thioaurone derivatives that afforded the hitherto unreported spiropyrazolines. Spectroscopic and spectrometric data were utilized to confirm
Mohamed Bakhouch +10 more
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