Results 161 to 170 of about 93,979 (223)

Dipolar Cycloaddition Reactions of Nitrilimines

open access: yesAustralian Journal of Chemistry, 1998
A series of ?-substituted a-methylidene-?-butyrolactone derivatives underwent regiospecific 1,3-dipolar cycloaddition with N -methyl- C -phenylnitrilimine. These reactions proceeded regiospecifically and with high diastereoselectivity, generally favouring the anti diastereomer as determined by n.m.r.
Dunstan, J.   +5 more
openaire   +3 more sources

Natural 1,3‐Dipolar Cycloadditions

Angewandte Chemie International Edition, 2015
[3+2] in the wild: Biomimetic natural product syntheses and theoretical considerations have indicated that 1,3-dipolar cycloadditions take place in nature. Now, the structure, biosynthesis, and function of a heavily modified prenylated flavin cofactor have been elucidated.
Martin, Baunach, Christian, Hertweck
openaire   +2 more sources

1,11-Dipolar cycloaddition

Journal of the Chemical Society, Chemical Communications, 1972
2-Methylnaphtho[1,8-de]triazine undergoes 1,11-dipolar (12π+ 2π) cycloaddition to acetylenic esters to give 2-methylacenaphtho[5,6-de]triazines, after spontaneous dehydrogenation.
C. W. Rees   +2 more
openaire   +1 more source

Extended dipolar cycloadditions

Journal of the Chemical Society, Perkin Transactions 1, 1975
Whilst the simple azomethine imine (5) undergoes the expected 1,3-dipolar cycloaddition to acetylenic esters, the extended azomethine imines (1) undergo 1,5-rather than 1,3-dipolar cycloaddition to give benzo[c][1,2,5]-triazepino[1,2-a]cinnolines (2), possibly by a stepwise mechanism 2-Alkyl-2λ5σ3-naphtho[1,8-de]triazines (12) and 2λ4σ2-naphtho[1,8-cd ...
Stephanie F. Gait   +4 more
openaire   +1 more source

Nanoparticle‐Catalysed 1,3‐Dipolar Cycloadditions

European Journal of Organic Chemistry, 2020
The 1,3‐dipolar cycloadditions of azomethine‐ylides and ‐imines, nitrones, nitrilimines, and azides catalysed by inorganic nanoparticles are described. Emphasis is given to the nanometric catalysts involved, their structure, characterisation, and recyclability and, when remarkable, their preparation.
Ponti A, Molteni G
openaire   +2 more sources

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