Atroposelective Synthesis of Axially Chiral Naphthylpyrroles by a Catalytic Asymmetric 1,3-Dipolar Cycloaddition/Aromatization Sequence. [PDF]
Maclean I +6 more
europepmc +1 more source
Density Functional Theory Calculations: A Useful Tool to Investigate Mechanisms of 1,3-Dipolar Cycloaddition Reactions. [PDF]
Chiacchio MA, Legnani L.
europepmc +1 more source
Diazomethyl-λ<sup>3</sup>-iodane meets aryne: dipolar cycloaddition and C-to-N iodane shift leading to indazolyl-λ<sup>3</sup>-iodanes. [PDF]
Otsuki S +5 more
europepmc +1 more source
Study on Regio- and Diastereoselectivity of the 1,3-Dipolar Cycloaddition Reaction of Azomethine Ylide with 2-(Benzo[d]thiazol-2-yl)-3-(aryl)acrylonitrile: Synthesis, Spectroscopic, and Computational Approach. [PDF]
Hussein EM +7 more
europepmc +1 more source
Ethynyl-substituted benzosiloxaboroles: the role of C(π)⋯B interactions in their crystal packing and use in Cu(i)-catalyzed 1,3-dipolar cycloaddition. [PDF]
Pacholak P +5 more
europepmc +1 more source
Dipolar Cycloaddition Reactions of Nitrilimines
A series of ?-substituted a-methylidene-?-butyrolactone derivatives underwent regiospecific 1,3-dipolar cycloaddition with N -methyl- C -phenylnitrilimine. These reactions proceeded regiospecifically and with high diastereoselectivity, generally favouring the anti diastereomer as determined by n.m.r.
Dunstan, J. +5 more
openaire +3 more sources
Related searches:
Natural 1,3‐Dipolar Cycloadditions
Angewandte Chemie International Edition, 2015[3+2] in the wild: Biomimetic natural product syntheses and theoretical considerations have indicated that 1,3-dipolar cycloadditions take place in nature. Now, the structure, biosynthesis, and function of a heavily modified prenylated flavin cofactor have been elucidated.
Martin, Baunach, Christian, Hertweck
openaire +2 more sources
2-Methylnaphtho[1,8-de]triazine undergoes 1,11-dipolar (12π+ 2π) cycloaddition to acetylenic esters to give 2-methylacenaphtho[5,6-de]triazines, after spontaneous dehydrogenation.
C. W. Rees +2 more
openaire +1 more source
Extended dipolar cycloadditions
Journal of the Chemical Society, Perkin Transactions 1, 1975Whilst the simple azomethine imine (5) undergoes the expected 1,3-dipolar cycloaddition to acetylenic esters, the extended azomethine imines (1) undergo 1,5-rather than 1,3-dipolar cycloaddition to give benzo[c][1,2,5]-triazepino[1,2-a]cinnolines (2), possibly by a stepwise mechanism 2-Alkyl-2λ5σ3-naphtho[1,8-de]triazines (12) and 2λ4σ2-naphtho[1,8-cd ...
Stephanie F. Gait +4 more
openaire +1 more source
Nanoparticle‐Catalysed 1,3‐Dipolar Cycloadditions
European Journal of Organic Chemistry, 2020The 1,3‐dipolar cycloadditions of azomethine‐ylides and ‐imines, nitrones, nitrilimines, and azides catalysed by inorganic nanoparticles are described. Emphasis is given to the nanometric catalysts involved, their structure, characterisation, and recyclability and, when remarkable, their preparation.
Ponti A, Molteni G
openaire +2 more sources

