Results 81 to 90 of about 93,979 (223)

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, Volume 38, Issue 51, 11 September 2026.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

Photo‐Triggered, Fast, and Fluorogenic Thiophene‐Based Cycloalkynes for the Bioorthogonal Fluorescent Labeling of 1,3‐Dipole‐Tagged Molecules in No‐Wash Conditions

open access: yesAngewandte Chemie, Volume 138, Issue 35, 24 August 2026.
Thiophene is king! The fusion of thiophene rings to cycloalkynes super‐charged their copper‐free click chemistry applications, by (1) enhancing the alkyne reactivity (fastest cyclooctyne to date) and (2) rendering the alkyne fluorogenic (with fluorescence enhancement up to 150‐fold upon reaction), making these bioorthogonal reagents ideal for tracking ...
Jurgen Schulz   +7 more
wiley   +2 more sources

A Chemical Framework for Engineering Extracellular Vesicles’ Biointerface to Advance Precision Therapeutics

open access: yesAdvanced Materials, Volume 38, Issue 52, 16 September 2026.
Extracellular vesicles (EVs) are cell‐derived nanoparticles that mediate intercellular communication through their dynamic biointerfaces. Owing to their intrinsic biological functions, EVs have emerged as promising platforms for biomedical applications.
Leila Pourtalebi Jahromi   +3 more
wiley   +1 more source

Ambimodal Dipolar/Diels–Alder Cycloaddition Transition States Involving Proton Transfers

open access: yes, 2018
Quantum mechanical computations and molecular dynamics simulations have been used to elucidate the factors that control reaction outcomes in ambi­modal transition states leading to both dipolar and Diels–Alder cycloaddition products, which can ...
K. N. Houk   +5 more
core   +1 more source

Alkylation and 1,3-Dipolar Cycloaddition of 6-Styryl-4,5-dihydro-2H-pyridazin-3-one: Synthesis of Novel N-Substituted Pyridazinones and Triazolo[4,3-b]pyridazinones

open access: yesJournal of Chemistry, 2013
Some new N-substituted pyridazinones and triazolo[4,3-b]pyridazinones were synthesized, respectively, by simple alkylation and 1,3-dipolar cycloaddition of pyridazin-3-one with nitrile imines.
Souad Mojahidi   +6 more
doaj   +1 more source

Alkoxyallenes in Modern Synthesis: Reactivity, Catalysis, and Complexity Generation

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 17, 1 September 2026.
The last decade has witnessed a remarkable transformation in alkoxyallene chemistry. Although historically employed as synthetic equivalents of acrolein or as versatile 3C synthons, alkoxyallenes are now increasingly recognized as highly adaptable platforms for synthetic design.
A. Lanfranco   +5 more
wiley   +1 more source

Metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrile oxides [PDF]

open access: yes, 2018
In the present review advances in the metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrile oxides, mainly in the last decade, will be presented and discussed. An overview on the structure, preparation, dimerization and related reactions as well
Roscales García, Silvia   +3 more
core   +1 more source

Crystal structure of (2R*,3aR*)-2-phenylsulfonyl-2,3,3a,4,5,6-hexahydropyrrolo[1,2-b]isoxazole

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
The title compound, C12H15NO3S, was prepared by 1,3-dipolar cycloaddition of 3,4-dihydro-2H-pyrrole 1-oxide and phenyl vinyl sulfone. In the molecule, both fused five-membered rings display a twisted conformation.
Yaiza Hernández   +4 more
doaj   +1 more source

Die Jekyll‐und‐Hyde‐Natur von Tetrazolen in der Polymerwissenschaft: Von der intrinsischen elektronischen Dualität zur programmierbaren makromolekularen Funktion

open access: yesAngewandte Chemie, Volume 138, Issue 36, 1 September 2026.
Ein Heterocyclus – drei elektronische Identitäten. Dieses Minireview zeigt, wie das Substitutionsmuster von Tetrazolen deren Funktion in Polymeren bestimmt und eröffnet substitutionsdefinierte Designprinzipien für funktionelle Polymermaterialien. ZUSAMMENFASSUNG Die Natur vereint Stabilität und Responsivität in einzelnen molekularen Gerüsten und ...
Meryem S. Akdemir, Hatice Mutlu
wiley   +1 more source

Novel valdecoxib derivatives by ruthenium(ii)-promoted 1,3-dipolar cycloaddition of nitrile oxides with alkynes – synthesis and COX-2 inhibition activity

open access: yes, 2018
By Ru(ii)-promoted 1,3-dipolar cycloaddition of nitrile oxides with alkynes 3,4-diaryl-substituted isoxazoles are formed in one step, showing high inhibition potency for COX-2.
Roscales García, Silvia   +11 more
core   +1 more source

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