A Novel Cycloaddition Reaction of Thermally Generated Sulfenes
The highly strained ?-sultine 4, resulting from the addition of SO2 to benzobenzvalene, is shown to undergo a thermal cycloreversion which gives 1H-indene-1-thiocarbaldehyde dioxide (6) as an intermediate and subsequently 1H-indene-1 ...
Ulrich Burger +3 more
doaj +2 more sources
Acceleration of 1,3-Dipolar Cycloadditions by Integration of Strain and Electronic Tuning. [PDF]
Dones JM +4 more
europepmc +1 more source
An overview of the cycloaddition chemistry of fulvenes and emerging applications
The unusual electronic properties and unique reactivity of fulvenes have interested researchers for over a century. The propensity to form dipolar structures at relatively low temperatures and to participate as various components in cycloaddition ...
Ellen Swan +2 more
doaj +1 more source
Regio- and Diastereoselective 1,3-Dipolar Cycloadditions of 1,2,4-Triazin-1-ium Ylides: a Straightforward Synthetic Route to Polysubstituted Pyrrolo[2,1-f][1,2,4]triazines. [PDF]
Galeta J +3 more
europepmc +1 more source
Nitropyridines as 2π-Partners in 1,3-Dipolar Cycloadditions with N-Methyl Azomethine Ylide: An Easy Access to Condensed Pyrrolines. [PDF]
Bastrakov MA +3 more
europepmc +1 more source
1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with nitrile oxides and nitrones
1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with nitrile oxides and nitrones is described. A series of novel isoxazolines are isolated from the nitrile oxide cycloadditions, whilst the isoxazolines generated from the nitrone cycloadditions ...
Lawrence, Simon E. +2 more
core +1 more source
1,2,4‐Oxadiazole[4,5‐a]piridinium chloride adds nucleophiles to undergo electrocyclic ring opening affording 1,2,4‐oxadiazole dienamino derivatives. These pyridinium salts represent a special class of Zincke salts that are prone to rearrange when treated
Dr. Stefano Carella +2 more
doaj +1 more source
Synthesis of chiral-at-metal rhodium complexes from achiral tripodal tetradentate ligands: resolution and application to enantioselective Diels-Alder and 1,3-dipolar cycloadditions. [PDF]
Tejero AG +6 more
europepmc +1 more source
Cycloadditions in modern polymer chemistry
ConspectusSynthetic polymer chemistry has undergone two major developments in the last two decades. About 20 years ago, reversible-deactivation radical polymerization processes started to give access to a wide range of polymeric architectures made from ...
Guimard, N. K. +2 more
core +1 more source
Quantitative Dynamics of the N2O + C2H2 → Oxadiazole Reaction: A Model for 1,3-Dipolar Cycloadditions. [PDF]
Liu Y, Li J.
europepmc +1 more source

