Results 11 to 20 of about 2,174 (182)
Organic Diselenides: Versatile Reagents, Precursors, and Intriguing Biologically Active Compounds [PDF]
CHIMIA, 2017 In this account, we describe how some organic diselenides were successfully used in the past as reagents for asymmetric stereoselective synthesis and more recently as precursors of catalysts and reagents applied in new green protocols.
Claudio Santi +2 more
doaj +2 more sources
Beilstein Journal of Organic Chemistry, 2013 A novel method of photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides has been developed. Although the arylation reactions with triarylbismuthines are usually catalyzed by transition-metal complexes ...
Yohsuke Kobiki +3 more
doaj +2 more sources
NiH-Catalyzed Enantio- and Regioselective Hydroselenylation of Unactivated Alkenes. [PDF]
Adv Sci (Weinh)Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Kang HJ, Kim J, Hong S.
europepmc +2 more sources
Evaluation of peri-like fluorene and carbazole diselenides as glutathione peroxidase mimics [PDF]
, 2021 This thesis reports the synthesis and evaluation of 4, 5-disubstituted fluorene and carbazole diselenides as GPx mimics. Chapter 1 describes the role of glutathione peroxidase as an important mammalian antioxidant and investigations towards developing
Jagdev, Kesar
core +6 more sources
Electrochemical use of chiral non-racemic diselenides [PDF]
An electrochemical approach has previously been described for the selenenylation-deselenenylation of alkenes using diphenyl diselenide. The use of electrochemistry enabled diphenyl diselenide to be used in catalytic amounts to convert alkenes into ...
Cox, Matthew
core +6 more sources
Electrochemically Driven Regioselective Radical Functionalization of Allenes: Scope and Mechanistic Insights. [PDF]
Adv Sci (Weinh)Allenes emerge as powerful platforms for electrochemical functionalization through radical pathways. Selective radical addition at the central carbon triggers anodic oxidation and intramolecular cyclization, enabling efficient synthesis of oxazolines and oxazolidine‐2‐imines without external oxidants.
Pyne P +5 more
europepmc +2 more sources
Pharmaceuticals, 2023 Organoselenium compounds are well-known for their numerous biocapacities, which result from the uniqueness of the selenium atom and the possibility of constructing heterorganic molecules that can mimic the activity of selenoenzymes, crucial for a ...
Agata J. Pacuła-Miszewska +5 more
doaj +1 more source
Bis(2,6-di(pyridin-2-yl)pyridin-4-yl)-6,6′-(1,2-diselanediyl)dihexanoate
Molbank, 2023 The present paper describes the preparation and characterization of a new dinuclear ligand based on terpyridine featuring a diselenide unit. This new compound was synthesized in a two-step procedure that first involved the insertion of the diselenide ...
Evelyn Popa +4 more
doaj +1 more source
Synthesis and Application Dichalcogenides as Radical Reagents with Photochemical Technology
Molecules, 2023 Dichalcogenides (disulfides and diselenides), as reactants for organic transformations, are important and widely used because of their potential to react with nucleophiles, electrophilic reagents, and radical precursors.
Cairong Wang +5 more
doaj +1 more source
Glutathione Peroxidase-like Antioxidant Activity of Diaryl Diselenides: A Mechanistic Study
, 2016 The synthesis, structure, and thiol peroxidase-like antioxidant activities of several diaryl diselenides having intramolecularly coordinating amino groups are described.
Narayan S. Punekar (591564) +4 more
core +4 more sources