Pushing the limits of concertedness. A waltz of wandering carbocations. [PDF]
Among the array of complex terpene-forming carbocation cyclization/rearrangement reactions, the so-called "triple shift" reactions are among the most unexpected.
Castiñeira Reis, Marta +3 more
core
Production of ent-kaurene from lignocellulosic hydrolysate in Rhodosporidium toruloides. [PDF]
BACKGROUND:Rhodosporidium toruloides has emerged as a promising host for the production of bioproducts from lignocellulose, in part due to its ability to grow on lignocellulosic feedstocks, tolerate growth inhibitors, and co-utilize sugars and lignin ...
Burnum-Johnson, Kristin E +15 more
core +1 more source
Summary The oleoresin defense system of loblolly pine (Pinus taeda) protects trees from insects and pathogens and is an important source of renewable biofuels and chemicals, but the genetic basis of oleoresin production is poorly understood. We characterized the genetic architecture of oleoresin flow, resin canal number, stem wood terpene content, and ...
Mallory M. Morgan +13 more
wiley +1 more source
Structure Elucidation and Botanical Characterization of Diterpenes from a Specific Type of Bee Glue
Investigation of the single plant source bee glue type originating from Southern Australia resulted in the isolation and structure elucidation of major serrulatane diterpenes, novel 7,8,18-trihydroxyserrulat-14-ene (1), along with its oxidized product, 5,
Noushin Aminimoghadamfarouj +1 more
doaj +1 more source
Batch and flow electrochemical methods enable direct C‐7 oxidation of abietic and dehydroabietic acids from colophony or their methyl derivatives to the corresponding ketones, while a mediated protocol enables additional C‐15 oxygenation, providing sustainable and selective routes to diversified abietane derivatives.
Inês S. Martins +2 more
wiley +1 more source
Bioactive Compounds From Torbangun [Plectranthus Amboinicus (Lour.) Spreng] Chloroform Fraction Induce Apoptosis in Breast Cancer (Mcf-7 Cells) in Vitro [PDF]
Torbangun (Plectranthus amboinicus (Lour.) Spreng) is a medicinal plant that has been traditionally used in tropical countries to cure various illnesses.
Andarwulan, N. (Nuri) +3 more
core
Bioinspired Microphase‐Engineered Binders for Silicon Anodes
Inspired by the tough exoskeleton of Phloeodes diabolicus, a bio‐based binder featuring LRA–click chemistry and hierarchical crosslinking forms well‐defined microphase‐separated structures that enable robust silicon anodes. This system promotes the formation of a LiF–rich, ultrathin SEI (∼17 nm) with high modulus and ionic conductivity, ensuring long ...
Lirong Tang +15 more
wiley +1 more source
Guyonianin A and B, Two Polyester Diterpenes from Algerian
The dichloromethane extract of the aerial parts of Euphorbia guyoniana afforded two new polyester diterpenes, named guyonianin A and B, a rare class of bicyclic diterpenes.
Ahmed A. Ahmed +6 more
doaj +1 more source
Spread and Population Dynamics of Rugulopteryx okamurae Across the Azores Archipelago (NE Atlantic)
ABSTRACT Rugulopteryx okamurae is a recently introduced brown macroalga that has expanded rapidly across the Azores (NE Atlantic). This study provides an update of the archipelago‐wide spatial spread and the first assessment of its local population dynamics.
Ana L. Santos +9 more
wiley +1 more source
Seasonal Variation of Essential Oil Yield and Composition of Sage (Salvia officinalis L.) Grown in Castilla - La Mancha (Central Spain) [PDF]
Links between phenology, yield and composition of the essential oil of common sage, Salvia officinalis L., grown in Guadalajara (Central Spain) were determined in the different phases of the biological cycle during one year.
Arrabal Miguel, Carlos +2 more
core +3 more sources

