Results 141 to 150 of about 31,248,239 (272)

Grenzflächen‐Synergie zwischen Mn und Kohlenstoffnitrid ermöglicht die selektive photokatalytische C–H‐Chlorierung mittels Einzelatomkatalyse

Angewandte Chemie, EarlyView.
Ein Mangan‐Einzelatom‐Photokatalysator auf funktionalisiertem Kohlenstoffnitrid ermöglicht die selektive, durch sichtbares Licht angetriebene C(sp2)–H‐Chlorierung. DFT‐gestützte mechanistische Untersuchungen zeigen, dass die photoinduzierte Ladungstrennung NCS aktiviert, während isolierte Mn‐Zentren Mn–Cl‐Intermediate an der Katalysatorgrenzfläche ...
Jaro Vanderghinste, Prakash Kumar Sahoo, Xinbang Wu, Thanh Huyen Vuong, Anna Rokicińska, Susanna Monti, Giovanni Barcaro, Alina Skorynina, Aleksander Jaworski, Vivien Michaelis, Jabor Rabeah, Julia Bornhorst, Laura Simonelli, Piotr Kuśtrowski, Adam Slabon, Paul J. Dyson, Shoubhik Das   +16 more
wiley   +1 more source

Metal–Metal Cooperative C─F and S─F Bond Cleavage by Low‐Valent Tetracobalt Clusters and Water‐Assisted Fluoroarene Hydrodefluorination

Angewandte Chemie, EarlyView.
Self‐assembled tetrahedral CoI4 clusters supported by simple bipyridine‐based ligands undergo core rearrangement to cleave S─F and C(sp2)─F bond, forming fluoride‐bridged tetracobalt(II)‐oxo clusters, while exposure of cobalt(I) clusters to molecular oxygen yields cubane‐type cobalt(III) oxo clusters.
Hoan M. Dinh, Pavan K. Vardhanapu, Robert R. Fayzullin, Eugene Khaskin, Julia R. Khusnutdinova   +4 more
wiley   +2 more sources

Cobalt‐Catalyzed [2σ+2π] Cycloaddition via Site‐Selective Capture of Bicyclobutane Diradical

Angewandte Chemie, EarlyView.
We report a Co(II)‐catalyzed strategy that combines thermal activation of bicyclo[1.1.0]butane (BCBs) with site‐selective radical capture to furnish head‐to‐head fused bicyclo[2.1.1]hexanes via [2σ+2π] cycloaddition with indoles. Detailed mechanistic studies (31P NMR, EPR, CV, and DFT) support the catalytic pathway, while phosphine‐oxide trapping and X‐
Tanmayee Nanda, Alexander Umanzor, Julia Gartzke, Jeremy T. Maddigan‐Wyatt, Philipp Thielert, Stefan Weber, Sabine Richert, Shuming Chen, Daniel B. Werz   +8 more
wiley   +2 more sources

Enhancing Strategic Agility and Real Time Decision-Making in the Technology Sector: Exploring the Role of AI and e-HRM Systems. [PDF]

F1000Res
Ongesa Nyamboga T.
europepmc   +1 more source

Z‐Retentive Enantioselective Rh‐Catalyzed Hydroarylation of E,Z‐Dienes

Angewandte Chemie, EarlyView.
The Rh‐catalyzed hydroarylation of conjugated E,Z‐dienoates is found to proceed with high selectivity for addition to the E‐alkene unit. Mechanistic analysis of this Z‐retentive process points towards preferred binding of the E‐alkene unit to a Rh‐aryl species to give rise to the observed selectivity and that Rh‐enolate protonolysis to be turnover ...
Wesley McNutt, Hima Kozhummal, Abdullah Al‐Mashqbeh, Alex Brown, Rylan J. Lundgren   +4 more
wiley   +2 more sources

Adenylation Domain Engineering Enables Biosynthesis of an Improved Polymyxin Antibiotic

Angewandte Chemie, EarlyView.
To enable incorporation of l‐2‐aminodecanoic acid into polymyxin by fermentation, a single Trp‐to‐Ala substitution is rationally introduced into the adenylation‐domain residue of its nonribosomal peptide synthetase (NRPS) and efficiently switches substrate selectivity. The engineered strain produces biologically active Ada‐polymyxin, demonstrating that
Maximilian Müll, Pia Lanvers, Giulia Ravagnan, Kilian Klaus, Olena Nosovska, Ivan Vilotijevic, Jochen Schmid, Hajo Kries   +7 more
wiley   +2 more sources

SOD1:c.118G>A mutation in the Cimarrón Uruguayo dog: prevalence, drift dynamics, and structural effects. [PDF]

Braz J Vet Med
Artigas R, Menchaca C, Jara E, Mondino A, Vázquez N, Branda Sica A, Llambí S.   +6 more
europepmc   +1 more source

Safety and feasibility of a novel oesophageal stimulation protocol in modulating aerodigestive mechanisms and outcomes in infants at-risk for gastrostomy: a pilot study. [PDF]

EClinicalMedicine
Jadcherla SR, Helmick R, Osborn EK, Alshaikh ES.   +3 more
europepmc   +1 more source

Comparative Evaluation of 16S rRNA Target Regions Using PCR High-Resolution Melt Curve Analysis for Differentiation of Bacteria Associated with Bovine Mastitis. [PDF]

Microorganisms
Jember TF, Westman ME, Pant SD, Ghorashi SA.   +3 more
europepmc   +1 more source

HRM and Value Creation [PDF]

It’s conceptually attractive to look for connection between performance, HRM and economic situation. How measure epiphenomenon’s impact when we can’t isolate that from global strategy?
Michel PHILIP & Patrick Micheletti
core