Results 141 to 150 of about 667,303 (272)
Bifunctional Aziridines from Photochemically Generated FSO2NH2 for SuFEx Diversification of Alkenes
Photochemically generated FSO2NH2 serves as a safe, practical nitrene precursor for Rh‐catalyzed aziridination of alkenes, granting access to previously inaccessible fluorosulfonyl aziridines. These bifunctional electrophiles merge aziridine ring strain with SuFEx reactivity to provide a modular platform toward aliphatic sulfamoyl fluoride derivatives ...
Avinash Choudhury +3 more
wiley +2 more sources
EnzyKR: a chirality-aware deep learning model for predicting the outcomes of the hydrolase-catalyzed kinetic resolution. [PDF]
Ran X, Jiang Y, Shao Q, Yang ZJ.
europepmc +1 more source
Chiral thiols. Synthesis and enantiomeric excess determination
Chiral thiols are a class of chira compounds, which is gaining mone and nore attention the last decenniun. Especially α-mercaptocarboxylic acids are frequently found as a structunal unit in (biologically) important products. As a consequence, many synthetic analoga or derivatives of these natural products, but also other organosulfur compounds, have ...
openaire +1 more source
The design and synthesis of a linear tetradentate NCCN ligand incorporating two 1,2,3‐triazolin‐5‐ylidene mesoionic carbene donors, and its application to asymmetric iron catalysis is reported. This work represents the first example of an iron complex derived from a cis‐α‐coordinating tetradentate NCCN ligand, and notably, the first chiral iron ...
Lukas Hinterlang +3 more
wiley +1 more source
Synthesis of Enantiopure [3]Cyclorubicenes
Herein, we present a high yielding synthesis of enantiopure [3]cyclorubicene, which is a potential precursor for a Haeckelite nanotube. This macrocycle was studied for its electronic and chiroptical properties and exhibits one of the highest dissymmetry values reported for a nanohoop.
Moritz P. Schuldt +2 more
wiley +2 more sources
Magnetic circular dichroism in Archean atmosphere and asymmetric photolysis of biomolecules: enantiomeric excess of prebiotic sugar. [PDF]
Sharma A.
europepmc +1 more source
We synthesized a series of light to heavy fluorous Hoveyda–Grubbs precatalyst analogs modified in the alkoxybenzylidene part in positions 2 and 5 by long (fluorinated) ponytails and tested their activity in ring‐closing metathesis. The substitution mostly resulted in accelerated reaction but the precatalyst stability often decreased.
Pavlína Dundálková +4 more
wiley +1 more source
Platinum group pincer complexes are highly efficient catalysts. Additionally, their high activity enables challenging transformations with low catalyst loading. Herein, we summarize the most relevant advances of catalysis involving platinum group pincer complexes. The use of pincer complexes based on platinum group metals is undoubtedly one of the most
Juan S. Serrano‐García +4 more
wiley +1 more source
Titelbild: Determination of Enantiomeric Excess in Amine Derivatives with Molecular Self‐Assemblies (Angew. Chem. 24/2015) [PDF]
Elena G. Shcherbakova +4 more
openalex +1 more source

