Results 141 to 150 of about 667,303 (272)

Bifunctional Aziridines from Photochemically Generated FSO2NH2 for SuFEx Diversification of Alkenes

open access: yesAngewandte Chemie, Volume 138, Issue 2, 9 January 2026.
Photochemically generated FSO2NH2 serves as a safe, practical nitrene precursor for Rh‐catalyzed aziridination of alkenes, granting access to previously inaccessible fluorosulfonyl aziridines. These bifunctional electrophiles merge aziridine ring strain with SuFEx reactivity to provide a modular platform toward aliphatic sulfamoyl fluoride derivatives ...
Avinash Choudhury   +3 more
wiley   +2 more sources

Assessing the Use of 50% Enantiomeric Excess Bupivacaine-Loaded Microspheres after Sciatic Nerve Block in Rats

open access: diamond, 2011
Rohnelt Machado de Oliveira   +2 more
openalex   +1 more source

Chiral thiols. Synthesis and enantiomeric excess determination

open access: yes, 1987
Chiral thiols are a class of chira compounds, which is gaining mone and nore attention the last decenniun. Especially α-mercaptocarboxylic acids are frequently found as a structunal unit in (biologically) important products. As a consequence, many synthetic analoga or derivatives of these natural products, but also other organosulfur compounds, have ...
openaire   +1 more source

An Achiral Tetradentate Cis‐α‐Coordinating NCCN Ligand Gives Rise to a Configurationally Stable Chiral‐at‐Iron Complex for Enantioselective Catalysis

open access: yesChemistry – A European Journal, Volume 32, Issue 3, 16 January 2026.
The design and synthesis of a linear tetradentate NCCN ligand incorporating two 1,2,3‐triazolin‐5‐ylidene mesoionic carbene donors, and its application to asymmetric iron catalysis is reported. This work represents the first example of an iron complex derived from a cis‐α‐coordinating tetradentate NCCN ligand, and notably, the first chiral iron ...
Lukas Hinterlang   +3 more
wiley   +1 more source

Synthesis of Enantiopure [3]Cyclorubicenes

open access: yesAngewandte Chemie, Volume 138, Issue 1, 2 January 2026.
Herein, we present a high yielding synthesis of enantiopure [3]cyclorubicene, which is a potential precursor for a Haeckelite nanotube. This macrocycle was studied for its electronic and chiroptical properties and exhibits one of the highest dissymmetry values reported for a nanohoop.
Moritz P. Schuldt   +2 more
wiley   +2 more sources

Hoveyda–Grubbs 1st and 2nd Generation Precatalysts Modified in the Alkoxybenzylidene Part With Long (Fluorous) Chains: Catalytic Activity and Stability

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 2, January 16, 2026.
We synthesized a series of light to heavy fluorous Hoveyda–Grubbs precatalyst analogs modified in the alkoxybenzylidene part in positions 2 and 5 by long (fluorinated) ponytails and tested their activity in ring‐closing metathesis. The substitution mostly resulted in accelerated reaction but the precatalyst stability often decreased.
Pavlína Dundálková   +4 more
wiley   +1 more source

Recent Advances in Homogeneous Catalysis with Platinum Group Pincer Complexes: Hydrogen‐Mediated Transformations and Cross‐Coupling Reactions

open access: yesThe Chemical Record, Volume 26, Issue 1, January 10, 2026.
Platinum group pincer complexes are highly efficient catalysts. Additionally, their high activity enables challenging transformations with low catalyst loading. Herein, we summarize the most relevant advances of catalysis involving platinum group pincer complexes. The use of pincer complexes based on platinum group metals is undoubtedly one of the most
Juan S. Serrano‐García   +4 more
wiley   +1 more source

Titelbild: Determination of Enantiomeric Excess in Amine Derivatives with Molecular Self‐Assemblies (Angew. Chem. 24/2015) [PDF]

open access: bronze, 2015
Elena G. Shcherbakova   +4 more
openalex   +1 more source

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